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| 1 | Closed-loop hydrometallurgical treatment of end-of-life lithium ion batteries: Towards zero-waste process and metal recycling in advanced batteries显示文摘This work presents an enhanced hydrometallurgical process for recycling lithium ion batteries. First, endof-life batteries were processed in a physical pre-treatment plant to obtain a representative electrode material. The resulting leachate was purified forth by iron-precipitation, liquid–liquid extractions, and an innovative Li–Na separation, in order to obtain valuable products. These products include high-grade graphite, cobalt oxide(Co3O4, purity 83%), cobalt oxalate(CoC2O4, purity 96%), nickel oxide(Ni O, purity89%), and lithium carbonate(Li2CO3, purity 99.8%). The recovery rate was quantitative for graphite, between 80% and 85% for cobalt depending on the nature of the recovery method, 90% for nickel, and 72%for lithium. Secondary streams were also valorized to obtain sodium sulfate(Na2SO4, purity 96%), and MnCoFe2O4 magnetic nano-sorbents according to the zero-waste concept. In order to close the loop, recycled Co3O4 and NiO were used as conversion-type anode materials for advanced lithium ion batteries showing promising performances. | Thomas Abo Atia Giuseppe Elia Robert Hahn Pietro Altimari Francesca Pagnanelli | 2019 | Journal of Energy Chemistry2019,28,8: | 8 |
| 2 | High levels of bcl-2 messenger RNA detected by in situ hybridization in human hepatocellular and cholangiocellular carcinomas显示文摘 | FIORENTINO M D'ERRICO A ALTIMARI A | 1999 | Diagn Mol Pathol1999,8,4: | 1 |
| 3 | Predictive value of biological markers for hepatocellular carcinoma patients treated with orthotopic liver transplantation 显示文摘 | Fiorentino M Altimari A Ravaioli M | 2004 | Clin Cancer Res2004,10,: | 1 |
| 4 | Low p27 expression is an independent predictor of survival for patients with either hilar or peripheral intrahepatic cholangiocarcinoma 显示文摘 | Fiorentino M Altimari A D Errico A | 2001 | Clin Cancer Res2001,7,12: | 1 |
| 5 | Does Money Lead Inflation in the Euro Area?显示文摘 | Nicoletti Altimari Sergio | 2001 | ECB Working paper Series2001,,63: | 1 |
| 6 | High levels of BCL-2 messenger RNA detected by in situ hybridization in human hepatocellular and cholangiocellular carcinomas显示文摘 | Fiorentino M D'Errico A Altimari A | 1999 | Diagn Mol Pathol1999,8,4: | 1 |
| 7 | Predictive value of biological markers for hepatocellular carcinoma patients treated with orthotopic liver transplantation 显示文摘 | Fiorentino M Altimari A Ravaioli M | 2004 | Clin Cancer Res2004,10,5: | 1 |
| 8 | pH-sensitive drug delivery systems by radi- cal polymerization of gelatin derivatives 显示文摘 | Altimari I Spizzirri U G Iemma F | 2012 | Journal of Applied Polymer Science2012,125,4: | 1 |
| 9 | Predictive value of biological markers for hepatocellular rarrinoma patients treated with orthotopic liver transplantation显示文摘 | Fiorentino M Altimari A Ravaioli M | 2004 | Clin Cancer Res2004,10,5: | 1 |
| 10 | Acquired expression of p27 is a favorable prognostic indicator in patients with hepatocellular carcinoma显示文摘 | Fiorentino M Altimari A DErrico A | 2000 | Clin - Cancer - Res2000,6,10: | 1 |
| 11 | Full recycling of spent lithium ion batteries with production of core-shell nanowires//exfoliated graphite asymmetric supercapacitor显示文摘A novel process is reported which produces an asymmetric supercapacitor through the complete recycling of end-of-life lithium ion batteries.The electrodic powder recovered by industrial scale mechanical treatment of spent batteries was leached and the dissolved metals were precipitated as mixed metals carbonates.Nanowires battery-type positive electrodes were produced by electrodeposition into nanoporous alumina templates from the electrolytic baths prepared by dissolution of the precipitated carbonates.The impact of the different metals contained in the electrodic powder was evaluated by benchmarking the electrochemical performances of the recovered nanowires-based electrodes against electrodes produced by using high-purity salts.Presence of inactive Cu in the nanowires lowered the final capacitance of the electrodes while Ni showed a synergistic effect with cobalt providing a higher capacitance with respect to synthetic Co electrodes.The carbonaceous solid recovered after leaching was indepth characterized and tested as negative electrode.Both the chemical and electrochemical characterization indicate that the recovered graphite is characterized by the presence of oxygen functionalities introduced by the leaching treatment.This has led to the obtainment of a recovered graphite characterized by an XPS C/O ratio,Raman spectrum and morphology close to literature reports for reduced graphene oxide.The asymmetric supercapacitor assembled using the recovered nanowires-based positive electrodes and graphite as negative electrodes has shown a specific capacitance of 42 F g^(-1), computed including the whole weight of the positive electrode and recovered graphite,providing a maximum energy density of ~9 Wh kg^(-1) and a power density of 416 W kg^(-1) at 2.5 mA cm^(-2). | Pier Giorgio Schiavi Pietro Altimari Robertino Zanoni Francesca Pagnanelli | 2021 | Journal of Energy Chemistry2021,30,7: | 1 |
| 12 | High levels of Bcl-2 messenger RNA detected by in situ hybridization in human hepatocellular and cholangiocellular carcinomas显示文摘 | Fiorentino M D'Errico A Altimari A | 1999 | Diagnostic Molecular Pathology1999,8,4: | 1 |
| 13 | Increased expression of p16(INK4a) and p27 (Kip1) cyclin-dependent kinase inhibitor genes in aging human kidney and chronic allograft nephropathy显示文摘 | Chkhotua AB Gabusi E Altimari A | 2003 | Am J Kidney Dis2003,41,: | 1 |
| 14 | Increased expression of p16 (INK4a) and p27 (Kip1) cyclin-dependent kinase inhibitor genes in aging human kidney and chronic allograft nephropathy显示文摘 | Chkhotua AB Gabusi E Altimari A | 2003 | Am J Kidney Dis2003,41,6: | 1 |
| 15 | Acquired expression of P27 is a fa- vorable prognostic indicator in patients with hepatocellular carcinoma显示文摘 | Fiorentino M Altimari A grrico A | 2000 | Clin Cancer Res2000,6,: | 1 |
| 16 | Use of a somatostatin analog (SMS 201-955) in the glucagonoma syndrome显示文摘 | Altimari AF Bhoopalam N O' Dorsio T | 1986 | Surgery1986,100,6: | 1 |
| 17 | Acquired expression of p27 is a favorable prognostic indicator in patients with hepatocellular carcinoma显示文摘 | Fiorentino M Altimari A D'Errico A | 2000 | Clin Cancer Res2000,600,: | 1 |
| 18 | Acquired expression of p27 is a favorable prognostic indicator in patients with hepatocellular carcinoma显示文摘 | Fiorentino M Altimari A D'Errico A | 2000 | Clin Cancer Res2000,6,10: | 1 |
| 19 | Diagnostic role of circulating free plasma DNA detection in patients with localized prostate cancer 显示文摘 | Altimari A Grigioni A D Benedettini E Gabusi E Schiavina R Martinelli A | 2008 | Am J Clin Pathol2008,129,: | 1 |
| 20 | Predictive value of biological markers for hepatocellular carcinoma patients treated with orthotopic liver transplantation 显示文摘 | Fiorentino M Altimari A Ravaioli M | 2004 | Clin Cancer Res2004,10,5: | 1 |