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| 1 | Surface functionalized N-C-TiO_(2)/C nanocomposites derived from metal-organic framework in water vapour for enhanced photocatalytic H generation显示文摘Surface-functionalized nitrogen/carbon co-doped polymorphic TiO_(2) phase junction nanoparticles uniformly distributed in porous carbon matrix were synthesized by a simple one-step pyrolysis of titanium based metal-organic framework(MOF),NH_(2)-MIL^(-1)25(Ti) at 700℃ under water vapour atmosphere.Introducing water vapour during the pyrolysis of NH_(2)-MIL^(-1)25(Ti) not only functionalizes the derived porous carbon matrix with carboxyl groups but also forms additional oxygen-rich N like interstitial/intraband states lying above the valence band of TiO2 along with the self-doped carbo n,which further narrows the energy band gaps of polymorphic TiO2 nanoparticles that enhance photocatalytic charge transfer efficiency.Without co-catalyst,sample N-C-TiO2/CArW demonstrates H_(2) evolution activity of 426 μmol gcat-1h^(-1),which remarkably outperforms commercial TiO_(2)(P-25) and N-C-TiO_(2)/CAr with a 5-fold and 3-fold H_(2) generation,respectively.This study clearly shows that water vapour atmosphere during the pyrolysis increases the hydrophilicity of the Ti-MOF derived composites by functionalizing porous carbon matrix with carboxylic groups,as well as enhancing the electrical conductivity and charge transfer efficiency due to the formation of additional localized oxygen-rich N like interstitial/intraband states.This work also demonstrates that by optimizing the anatase-rutile phase composition of the TiO2 polymorphs,tuning the energy band gaps by N/C co-doping and functionalizing the porous carbon matrix in the N-C-TiO2/C nanocomposites,the photocatalytic H_(2) generation activity can be further enhanced. | Mian Zahid Hussain Zhuxian Yang Bart van der Linden Zheng Huang Quanli Jia Erik Cerrato Roland A.Fischer Freek Kapteijn Yanqiu Zhu Yongde Xia | 2021 | Journal of Energy Chemistry2021,30,6: | 3 |
| 2 | 欧洲和中国的心脏与肾脏远程缺血预适应研究:一项随机对照试验显示文摘远程缺血预适应(remote ischemic preconditioning,RIPC)对经皮冠状动脉介入治疗(percutaneous coronary intervention,PCI)术后造影剂肾病(contrast-induced nephropathy,CIN)的潜在保护作用尚待确定。该研究为双盲、随机、安慰剂对照的多中心研究,纳入年龄〈85岁,肾清除率为30~60mL/(min·1.73m^2)的有临床适应证的患者,除了直接PCI外均按1∶1给予RIPC或标准治疗。主要终点是CIN的发生率。次要终点是围手术期心肌梗死(peri-procedural myocardial infarction,PMI)的发生率。 | 刘青 叶鹏 Moretti C Cerrato E Cavallero E Lin S Rossi ML Picchi A Sanguineti F Ugo F Palazzuoli A Bertaina M Presbitero P Shao-Liang C Pozzi R Giammaria M Limbruno U Lefèvre T Gasparetto V Garbo R OmedèP Sheiban I Escaned J Biondi-Zoccai G Gaita F Perl L D'Ascenzo F | 2018 | 中华高血压杂志2018,26,4: | 3 |
| 3 | On the surface acidity of some sulfate-doped ZrO2 catalysts显示文摘 | MORTERRA C CERRATO G EMANUEL C | 1993 | Journal of Catalysis1993,142,2: | 1 |
| 4 | Comparison of models for describing corn yield response to nitrogen fertilizer 显示文摘 | Cerrato M E Blackmer A M | 1990 | Agronomy Journal1990,82,1: | 1 |
| 5 | Current management of tarsometatarsal in- juries in the athlete 显示文摘 | Myerson MS Cerrato RA | 2008 | J Bone Joint Surg Am2008,90,11: | 1 |
| 6 | The ultinational nterprise as an Internal Market System显示文摘 | Daniele Cerrato | 2006 | International Business Review2006,,15: | 1 |
| 7 | Electronic nose based on metal oxide semiconductor sensors as a fast ahemative for the detection of adulteration of virgin olive oils显示文摘 | Cerrato Oliveros M C P 6 rez Pav 6 n J L Garca Pinto C | 2002 | Analytica Chimica Acta2002,459,2: | 1 |
| 8 | Restricted dissociated sensory loss in a patient with a lateral medullary syndrome: A clinicalMRI study 显示文摘 | Cerrato P Imperiale D Bergui M | 2000 | Stroke2000,31,12: | 1 |
| 9 | Effect of the northern quahog Mercenaria mercenaria on the development of blooms of the brown tide alga Aureococcus anophagefferens 显示文摘 | CERRATO R CARON A LONSDALE J | 2004 | Mar Ecol Prog Ser2004,281,: | 1 |
| 10 | Atrial fibrillation in a large population with Brugada electrocardiographic pat- tern:prevalence, management and correlation with progno- sis显示文摘 | Giustetto C Cerrato N Gribaudo E | 2014 | Heart Rhythm2014,11,2: | 1 |
| 11 | Comparison of models for describing corn yield response to nitrogen fertilizer显示文摘 | Cerrato M E Blackmer A M | 1990 | Agronomy Journal1990,82,: | 1 |
| 12 | Likely serotoninergic syndrome from an interaction between amitryptiline,paroxetine,and linezolid显示文摘 | Morales-Molina JA Mateu-de Antonio J Grau Cerrato S Marín Casino M | 2005 | Farm Hosp2005,29,: | 1 |
| 13 | Electronic nose based on metal oxide semiconductor sensors and pattern recognition techniques: haracterization of vegetable oils显示文摘 | Yolanda Gonzalez Martin Concepcion Cerrato Oliveros M Jose Luis Perez Pavon | 2001 | Analytica Chimica Acta2001,449,: | 1 |
| 14 | Kiss1-/-mice exhibit more variable hy-pogonadism than Gpr54-/-mice显示文摘 | Lapatto R Pallais JC Zhang D Chan YM Mahan A Cerrato F | 2007 | Endocrinology2007,148,10: | 1 |
| 15 | Stroke in young patients : etiopathogenesis and risk factors in different age classes 显示文摘 | Cerrato P Grasso M Lmperiale D | 2004 | Cere- brovasc Dis2004,18,: | 1 |
| 16 | Time-course of cardi- ac remodeling following transeatheter closure of atrial septal defect 显示文摘 | Pascotto M Santoro G Cerrato F | 2006 | Int J Cardio12006,112,3: | 1 |
| 17 | Current management of tarsometatarsal injuries in the athlete显示文摘 | Myerson MS Cerrato RA | 2008 | J Bone Joint Surg Am2008,90,11: | 1 |
| 18 | Sources of intense geomagnetic storms over the rise of solar cycle 23显示文摘 | Cid C Hidalgo M A Saiz E Y Cerrato | 2004 | Solar Phys2004,,: | 1 |
| 19 | Psychosocial impact of adolescent gynecomastia:a prospective case-control study 显示文摘 | Nuzzi LC Cerrato FE Erickson CR | 2013 | Plast Surg2013,131,4: | 1 |
| 20 | Electronic nose based on metal oxide semiconductor sensors as a fast altemative for the detection of adulteration of virgin olive oils 显示文摘 | Ma Concepcin Cerrato 01iveros Jos Luis Prez Pavn Carmelo Garcl a Pinto | 2002 | Analytica Chimica Acta2002,,459: | 1 |