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| 1 | Laccase-catalyzed bisphenol A oxidation in the presence of 10-propyl sulfonic acid phenoxazine显示文摘The kinetics of the Coriolopsis byrsina laccase-catalyzed bisphenol A(BisA) oxidation was investigated in the absence and presence of electron-transfer mediator 3-phenoxazin-10-ylpropane-1-sulfonic acid(PPSA) at pH 5.5 and 25°C. It was shown that oxidation rate of the hardly degrading compound BisA increased in the presence of the highly reactive substrate PPSA. The increase of reaction rate depends on PPSA and BisA concentrations as well on their ratio, e.g., at0.2 mmol/L of BisA and 2 μmol/L of PPSA the rate increased 2 times. The kinetic data were analyzed using a scheme of synergistic laccase-catalyzed BisA oxidation. The calculated constant, characterizing reactivity of PPSA with laccase, is almost 1000 times higher than the constant, characterizing reactivity of BisA with laccase. This means that mediator-assisted BisA oxidation rate can be 1000 times higher in comparison to non-mediator reaction if compounds concentration is equal but very low. | Ruta Ivanec-Goranina Juozas Kulys Irina Bachmatova Liucija Marcinkeviciene Rolandas Meskys | 2015 | Journal of Environmental Sciences2015,27,4: | 3 |
| 2 | Effects of rhamnolipid biosurfactant JBR425 and synthetic surfactant Surfynol465 on the peroxidase-catalyzed oxidation of 2-naphthol显示文摘The kinetics of the recombinant Coprinus cinereus peroxidase-catalyzed2-naphthol oxidationwas investigated in the presence of rhamnolipid biosurfactant JBR425 and synthetic surfactant Surfynol465 at pH 5.5 and25°C,with concentrations of (bio)surfactants both less than critical micelle concentrations (CMC) and larger than CMC. Itwas shown that monomers of JBR425 aswell as monomers of Surfynol465 had an enhancing effect on the conversion of2-naphthol indose response manner anddid not influence the initial rate of 2-naphthol oxidation. The resultswere accounted by a scheme,which contains a stadium of enzyme inhibition by oligomeric2- naphthol oxidation products. The action of the biosurfactant's (or synthetic surfactant's) monomerswas explained by avoidance of the enzyme active center clothingwith oligomers. Similar results havedemonstrated the potential of rhamnolipid biosurfactant JBR425due to its biodegradability. When biosurfactants' concentrations are larger than CMC, (bio)surfactants have an opposite effect on the oxidation of2-naphthol by peroxidase. | Ivanec-Goranina Rūta Kulys Juozas | 2013 | Journal of Environmental Sciences2013,25,7: | 2 |
| 3 | Electrocataslytic oxidation of ascorbic acid at chemically modifed electrodes显示文摘 | Kulys J Drungiliene A | 1991 | Electroanalysis1991,3,: | 2 |
| 4 | Effects of aggressive approach to the multiple risk factors for diabetic nephro-pathy on proteinuria reduction in diabetes type 2 patients显示文摘 | Asci-Buturovi B Kacila M Kuli M | 2009 | Bosn J Basic Med Sci2009,9,1: | 1 |
| 5 | Redox chemistry in laccase-catalyzed oxidation of N-hydroxy compounds显示文摘 | Xu F Kulys J J Duke K | 2000 | Applied and Environmental Microbiology2000,66,5: | 1 |
| 6 | DNA methylation and cancer显示文摘 | KULIS M ESTELLER M | 2010 | Adv Genet2010,70,: | 1 |
| 7 | Amperometric Biosensors Based on Recombinant Laccases for Phenols Determination显示文摘 | Kulys J Vidziunaite R | 2003 | Biosens Bioelectron2003,,18: | 1 |
| 8 | Occurrence of antibiotics in hospital, residential, and dairy effluent, municipal wastewater, and the Rio Grande in New Mexico显示文摘 | BROWN K D KULIS J THOMSON B | 2006 | Science of the Total Environment2006,366,23: | 1 |
| 9 | DNA methylation and cancer显示文摘 | Kulis M Esteller M | 2010 | Adv Gen- et2010,70,: | 1 |
| 10 | Semi-supervised graph clustering:a kernel approach显示文摘 | Kulis B Basu S Dhillon I | 2009 | Machine learning2009,74,1: | 1 |
| 11 | Recent trends in the de- velopment of health management 显示文摘 | Edingtond W Louis Y Ku KulI | 2001 | Health Management Re- search2001,76,103: | 1 |
| 12 | Semi -Supervised Graph Clustering:A Kernel Approach显示文摘 | Brian Kulis Sugato Basu | 2009 | Machine Learning2009,74,1: | 1 |
| 13 | DNA methylafion and cancer显示文摘 | Kulis M Esteller M | 2010 | Adv Genet2010,70,: | 1 |
| 14 | An immunofluorescent survey of the brown tide chrysophyte Aureococcus anophagefferens along the Northeast coast of the United-States显示文摘 | Anderson D M Keafer B A Kulis D M | 1993 | Journal of Plankton Research1993,15,5: | 1 |
| 15 | Ab initio calculation of the electronic structure and spectroscopic properties of spinel gamma-Sn《,3》N《,4》显示文摘 | | 2006 | Physical Review B2006,73,04: | 1 |
| 16 | Vitamin D: an evi- dence-based review显示文摘 | Kulie T Groff A Redmer J | 2009 | J Am Board Fam Med2009,22,6: | 1 |
| 17 | Fast similarity search for learned metrics 显示文摘 | Kulis B Jain P Grauman K | 2009 | IEEE Transactions on Pattern Analysis and Ma- chine InteUigence2009,31,12: | 1 |
| 18 | Paralytic shellfish poisoning in Southern China显示文摘 | ANDERSON D M KULIS D M QI Y Z | 1996 | Toxicon1996,34,5: | 1 |
| 19 | Laparoscopic adrenalectomy:lessons learned from 306 cases显示文摘 | Kulis T Knezevic N Pekez M | 2012 | J Laparoendosc Adv Surg Tech2012,22,1: | 1 |
| 20 | Paralytic shellfish poisoning in Southern China显示文摘 | Anderson D M Kulis D M Qi Y Z | 1996 | Toxicon1996,,34: | 1 |