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1稀土对6063Al镍基激光熔覆层组织及摩擦磨损性能的影响显示文摘利用激光熔覆技术,在6063Al表面制备了添加有La2O3、Y2O3、Ce O2的Ni60合金熔覆层,并通过SEM、XRD、显微硬度计和摩擦磨损试验机等设备的测试分析,研究稀土氧化物对6063Al表面Ni基激光熔覆层组织结构、硬度及摩擦磨损性能的影响.结果表明:不同成分熔覆层的主要相结构均为β-Ni Al(Cr)和少量的Al3Ni、Al Ni3和Al等,但La2O3+Ni60熔覆层中含稀土化合物Al4La,Y2O3+Ni60熔覆层中出现了YAl3、Al Ni Y和Ni17Y2,Ce O2+Ni60熔覆层中检测到了Ce Ni5和Ce3Ni6Si2;添加不同稀土氧化物的Ni60熔覆层呈现细密的、均匀分布的枝晶,无明显气孔,其晶粒较不含稀土的Ni60熔覆层明显细化;加入稀土氧化物的Ni60熔覆层硬度提高HV100~300,且随着深度的增加,硬度值比未加稀土的Ni60熔覆层过渡较平缓;和Ni60熔覆层相比,添加稀土氧化物La2O3、Y2O3和Ce O2的Ni60熔覆层磨损面崩损程度减小了,具有较平整的表面磨痕形貌,磨痕深度和宽度均大幅减小,磨损量减少了一个数量级,摩擦系数也较低,其中加入La2O3和Ce O2的熔覆层磨损量最低,耐磨性最好.张光耀 王成磊 高原 宋沂泽 2015摩擦学学报2015,35,3:13
2Microstructure and wear-resistant properties of NiCr–Cr_3C_2 coating with Ni45 transition layer produced by laser cladding显示文摘NiCr–Cr3C2 metal–ceramic composite coating is commonly produced on metal substrate by laser cladding to be used as wear-resistant coating under medium- or high-temperature working conditions.The coating has high hardness, generally over three times that of the substrate.In order to make the hardness increase gradually from substrate to coating surface, the nickel-based alloy Ni45 was chosen as the transition layer and Ni Cr–Cr3C2 coating was indirectly cladded on 20Cr2Ni4 A substrate.Microstructure and composition of the coating were characterized by scanning electron microscope(SEM), energy-dispersive spectroscopy(EDS) and X-ray diffraction(XRD).Microhardness of the cross section of the coating was measured.Friction and wear behavior of Ni Cr–Cr3C2coating and substrate were investigated through sliding against the Si C ball at 20, 100 and 300 °C.The morphologies of worn surfaces were analyzed by SEM and EDS.The results show that the hardness of Ni45 transition layer is between that of the substrate and Ni Cr–Cr3C2coating, which avoids hardness jump and stress concentration of the coating.Ni Cr–Cr3C2coating contains hard phases of Cr3C2 and Cr7C3which enhance the wear resistance.With thetemperature increasing, friction coefficient and wear rate of the substrate increase significantly.Compared with the substrate, Ni Cr–Cr3C2coating has lower friction coefficient and wear rate at 100 and 300 °C, which verifies the good wear resistance of NiCr–Cr3C2 coating.Chun-Cheng Zang Yan-Zhong Wang Yi-Du Zhang Jin-Hua Li Hong Zeng De-Qiang Zhang 2015Rare Metals2015,34,7:9
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