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| 1 | 相变离子液体体系吸收分离CO_(2)的研究现状及展望显示文摘全球工业化的迅速发展及人口增长使得化石燃料消耗不断增加,导致二氧化碳(CO_(2))排放量逐年递增,引发全球化气候问题。醇胺吸收法目前在工业CO_(2)捕集应用最广泛,主要以单乙醇胺、甲基二乙醇胺等水溶液为吸收剂,存在溶剂损耗大、再生能耗高等问题,开发高效低能耗的新型吸收剂是实现CO_(2)大规模捕集的关键。离子液体具有气体亲和性好、蒸气压低、结构性质可调等特点,其中相变离子液体体系因节能潜力大被认为是新一代CO_(2)吸收剂,其吸收CO_(2)后由均相变为互不相溶的液-液或液-固两相,再生时仅需对CO_(2)富相加热处理,可有效减少吸收剂再生体积,降低再生能耗。重点总结近五年相变离子液体体系在CO_(2)分离的研究现状和进展,对不同相变行为的液-液和液-固相变离子液体体系分类阐述和讨论,并对其发展趋势进行展望。 | 杨灿 孙雪琦 尚明华 张建 张香平 曾少娟 | 2023 | 化工学报2023，74，4： | 2 |
| 2 | Dynamic chemistry in ionic liquid-based conductor显示文摘Ionic liquids,as a kind of liquid conductors with the unique inherent abilities of rapid self-healing,highly adaptive deformation,reconstruction,as well as high ionic conductivity,have been highly praised and recommended as a new competitive conducting material for green electronics.However,ionic liquids are likely encountered with the leakage problems when they are integrated into electronic devices.This issue as well as the need to develop intelligent electronics stimulate the innovation of ionic liquids with response characters besides conducting performance.Some'innovative'or'functional'ionic liquids consisting dynamic chemical bonds can reversibly switch between different states in response to external stimuli.These specialized ionic liquids afford powerful supplements to minimize the issue of leakage of ionic liquid conductors from electrical circuits,and also exhibit the properties of self-healing,reprocessing,adaptive deformation,which accord with the forthcoming era of Internet of Things.This minireview systematically summarizes the progresses of ionic liquid-based conductors containing dynamic bonds,particularly highlighting their applicable merits in self-healing,stretchable,and recyclable aspects.We also discuss the challenges in the next period and describe an unambiguous future of this research area. | Zhiwu Chen Qinyuan Gui Yapei Wang | 2021 | Green Chemical Engineering2021，2，4： | 1 |
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