Enhancement of Sensitivity for Determination of Phenols in Environmental Water Samples by Single-drop Liquid Phase Microextraction Using Ionic Liquid prior to HPLC

查看全文 作　　者：Qing Xiang [1]ZHOU;Jun Ping [2]XIAO;Cun Ling [1,3]YE;Xin Ming [3]WANG 机构地区：[1]School of Chemistry and Environmental Sciences, Henan Key Laboratory for Environmental Pollution Control, Henan Normal University, Xinxiang 453007;[2]Department of Chemistry, University of Science and Technology Beijing, Beijing 100083;[3]State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640 出　　处：《Chinese Chemical Letters》索引2006年第17卷第8期,共4页 摘　　要：A single-drop liquid phase micro-extraction procedure using 1-butyl-3-methylimidazo- lium hexafluorophosphate ([C4MIM][PF6]) was demonstrated for the sensitive determination of four phenols in water samples. Under the optimized conditions, the linear range of proposed method was excellent in the range of 0.5-100 μg·L-1, the reproducibility (RSD, n=6) were in the range 5.4%-8.9% and detection limits (S/N=3) were 0.3, 0.3, 0.5 and 0.5 μg·L-1 for 2, 4-dichloro- phenol, 2-naphthol, 2-nitrophenol and 4-chlorophenol, respectively. The experimental results indicated that the effect of complex matrices natural water samples could be resolved with addition of sodium ethylene diamine tetracetate (EDTA) into the samples. Excellent spiked recoveries were achieved for these four phenols ranged from 86.2%-114.9 %. All these facts demonstrated that the proposed method with merits of low cost, simplicity and easy operating would be a competitive alternative procedure for the determination of such compounds at trace level. 关 键 词：1-丁基-3-甲基咪唑六氟磷酸酯 单一液相微萃取 苯酚 离子液体 环境污染 环境分析