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Synthesis of 4″-benzyloxyimino-4″-deoxyavermectin Bla derivatives

查看全文 作  者:Yue Mei [1]Jia;Xiao Mei [1]Liang;Xue [1]Qin.Fang;Jing Ping [1]Wu;Dao Quan [1]Wang;Chang Hui [2]Rui;Xian Lin [2]Fan;Hai Yan [2]Zhao;Yun Xia [2]Wang 高影响力作者 机构地区:[1]Department of Applied Chemistry, China Agricultural University, Beijing 100094, China;[2]Institute of Plant Protection, Chinese Academy of Agricultural Science, Beijing 100094, China高影响力机构 出  处:《Chinese Chemical Letters》索引2007年第18卷第8期,共4页高影响力期刊 摘  要:Six new 4″-benzyloxyimino-4″-deoxyavermectin Bla derivatives were synthesized from avermectin Bla by the selective protection of C-5-hydroxy group,oxidation of C-4″-hydroxy group,and deprotection followed by reaction with O-substituted hydroxylamine hydrochlorides.Their structures were confirmed by IR,~1H NMR,^(13)C NMR and MS.Insecticidal activities of the derivatives against Phopalosiphum pseudobrassicae,Spodoptera exigua and Pluteua xylosteua were evaluated. 关 键 词:除虫菌素 合成 4-苄氧基亚氨基 杀虫剂 杀虫活性
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