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Synthesis of a Novel UV-curable Prepolymer Polypropyleneglycol Diglycidyl Ether Diacrylate

查看全文 作  者:HUANG Biwu HUANG Bofen DU Guoping CHEN [1]Weiqing 高影响力作者 机构地区:[1]School of Material Science and Engineering, Nanchang University, Nanchang 330031, China高影响力机构 出  处:《Journal of Wuhan University of Technology(Materials Science)》索引2008年第23卷第4期,共4页高影响力期刊 基  金:the Innovatory Group Program of the Natural Science Foundation of Hubei Province(No.2004ABC001);the National'863'Hi-tech Foundation of China(No.2002AA6Z3083) 摘  要:A novel UV-curable prepolymer polypropyleneglycol diglycidyl ether diacrylate(PPGGEA) was synthesized by utilizing polypropyleneglycol diglycidyl ether(PPGGE)and acrylic acid(AA)as starting materials,N,N-dimethylbenzylamine as catalyst and p-hydroxyanisole as inhibitor.The optimum synthetic conditions were in the following:the concentration of N,N-dimethylbenzylamine was 0.80 wt%of reactants,the concentration of p-hydroxyanisole was 0.3 wt%of reactants,the reaction temperature was 90-110℃,and the molar ratio of PPGGE to AA was 1:2.2.Meanwhile,1-hydroxycyclohexyl phenyl ketone of a UV-cured initiator was added to the synthesized PPGGEA to prepare a kind of UV-cured coating.The mechanical properties of the UV-cured films were determined,giving 29.99 MPa of tensile strength,834.27 MPa of the Young's modulus and 5.66% of elongation at tear. 关 键 词:预聚物 丙烯酸 薄膜 聚丙烯乙二醇
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