Synthesis of fulleropyrrolidine derivatives of C_(60)

查看全文 作　　者：LI Yuliang, ZHENG Dagui, XU Juhua, MAO Zhong, YANG Jingkui, BAI Fenglian and ZHU DaobenInstitute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China 出　　处：《Chinese Science Bulletin》索引1997年第42卷第14期,共5页 摘　　要：1 Experimental ORGANIC chemical derivatization of fullerene by cycloaddition reactions has attracted in-tense interest. It has been found that C₆₀ can undergo a series of cycloaddition reactions associ-ated with poorly-conjugated and electron-deficient alkenes, including [4+2], [3+2], [2+2] and [2+1] cycloaddition reaction, 1, 3-dipolar cycloaddition reactions. [3+2] cycloaddi-tion reactions of azomethine ylides to C₆₀ have been widely used to prepare N-substituted 关 键 词：FULLERENE PYRROLIDINE 1 3-dipolar.