Grain Growth Kinetics and Debye Temperature of Nanometer TiO_2 Powders Prepared by a Sol-gel Process

查看全文 作　　者：Ju LUO;Xingzhao DING;Benpei CHEN and Jie KONG(Institute of Solid State Physics, Academia Sinica, Hefei, 230031, China)Yuanda DONG(Dept. of Metallurgy and Materials, Shanghai University of Technology, Shanghai, 200072, China) 出　　处：《Journal of Materials Science & Technology》索引1994年第10卷第3期,共4页 摘　　要：The development of microstructure of nanometer TiO2 powders prepared by a sol-gel process was systematically studied. Grain growth was mon itored using X-ray diffraction (XRD) and transmission electron microscopy (TEM). and the Debye temperature of anatase crystallites was determined. It was found that the grain size of the powders increased slowly with annealing temperature up to 773 K. but grew rapidly in the temperature range of 773-1273K. The activation energies (Ea) for the growth of anatase crystallites in the two temperature regions were calculated to be 16 and 90 kJ / mol, respectively. The Debye temperatures of nanocrystalline anatase powders were all lower than that of microcrystalline anatase. which implies that the bonding force between Ti and O atoms in nanocrystalline TiO2 shourd be smaller than that in microcrystalline state. However. it was noted that the Debye temperature of nanocrystalline anatase increased with the decrease of grain size. This may be attributed to the enhancement in atomic bonding force due to the existence of high surface tension in nanocrystalline 关 键 词：Grain DEBYE Ceram SAKAI POWDERS HARDNESS FIGURE ETOH CHENG