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Characteristics of oxygen consumption of coal at programmed temperatures

查看全文 作  者:QI [1]Xuyao;WANG [1]Deming;ZHONG [1]Xiaoxing;GU [1]Junjie;XU [1]Tao 高影响力作者 机构地区:[1]State Key Laboratory of Coal Resources and Safe Mining,School of Safety Engineering,China University of Mining&Technology,Xuzhou 221008,China高影响力机构 出  处:《Mining Science and Technology》索引2010年第20卷第3期,共6页高影响力期刊 基  金:Financial support for this research from the National Natural Science Foundation of China(Nos. 50674088 and 50927403) 摘  要:Oxygen consumption is an important index of coal oxidation.In order to explore the coal-oxygen reaction,we developed an experimental system of coal spontaneous combustion and tested oxygen consumption of differently ranked coals at programmed temperatures.The size of coal samples ranged from 0.18~0.42 mm and the system heat-rate was 0.8℃/min.The results show that, for high ranked coals,oxygen consumption rises with coal temperature as a piecewise non-linear process.The critical coal temperature is about 50℃.Below this temperature,oxygen consumption decreases with rising coal temperatures and reached a minimum at 50℃,approximately.Subsequently,it begins to increase and the rate of growth clearly increased with temperature.For low ranked coals,this characteristic is inconspicuous or even non-existent.The difference in oxygen consumption at the same temperatures varies for differently ranked coals.The results show the difference in oxygen consumption of the coals tested in our study reached 78.6%at 100℃.Based on the theory of coal-oxygen reaction,these phenomena were analyzed from the point of view of physical and chemical characteristics,as well as the appearance of the coal-oxygen complex.From theoretical analyses and our experiments,we conclude that the oxygen consumption at programmed temperatures reflects the oxidation ability of coals perfectly. 关 键 词:oxygen consumption differently ranked coals programmed temperatures piecewise non-linear process oxidation ability
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