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Fabrication of ZnO-based thick film varistors with high potential gradient

查看全文 作  者:KE Lei JIANG Dongmei MA [1]Xueming 高影响力作者 机构地区:[1]State Key Laboratory of Precision Spectroscopy, Department of Physics, East China Normal University, Shanghai 200062, China高影响力机构 出  处:《Rare Metals》索引2010年第29卷第4期,共6页高影响力期刊 基  金:supported by the Nano Special Plan from Shanghai Municipal Science and Technology Plan of Commission (No 0852nm06000);the Shanghai Municipal Natural Science Foundation (No 08ZR1406700) 摘  要:ZnO-based thick film varistors have been fabricated by Y2O3 doping and low-temperature sintering,of which the sample with the best electrical properties has a high potential gradient value of 3159.4 V/mm.The effects of Y2O3 doping concentration and sintering temperature on the potential gradient of the samples were systematically investigated.The results show that the sample with the best electrical properties can be obtained by doping 0.08 mol% Y2O3 and sintering at 725℃.Under these optimum preparation conditions,the leakage current and the nonlinear coefficient are found to be 36.4 μA and 13.1.The sample with the best electrical properties has a grain size of 1.290 μm,a single grain boundary voltage of 4.08 V,a barrier height of 0.81 eV,and a depletion layer width of 10.2 nm,which are determined by thermionic emission.Small grain size with good grain boundary characteristics is beneficial to improve the electrical properties of varistors and promote the potential gradient. 关 键 词:高电位梯度 压敏电阻 制备条件 氧化锌 厚膜 基础 低温烧结 掺杂浓度
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