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Changes of Oxygen Content in Molten TiAl Alloys as a Function of Superheat during Vacuum Induction Melting

查看全文 作  者:Bo Chen,Yingche Ma,Ming Gao and Kui Liu Institute of Metal Research,Chinese Academy of sciences,Shenyang 110016,China 高影响力作者 出  处:《Journal of Materials Science & Technology》索引2010年第26卷第10期,共4页高影响力期刊 摘  要:Experimental studies on the melting process of titanium aluminum alloy have been pursued from the viewpoint of contamination.TiAl alloys were prepared with vacuum induction melting (VIM) in calcia crucibles at 1873 K and 1923 K in order to determine the behavior of the oxygen content as a function of temperature,time and frequency of power.The experiment results showed that alloys were uncontaminated except for the increasing of oxygen content which was introduced from the reaction CaO(s)=Ca(in TiAl)+O(in TiAl),and the standard Gibbs energy of the reaction was determined to be △G0 =274000 102.8T(J/mol).Oxygen content increased slowly with the melting time by about 50×10-6 wt pct/min,and decreased with induction melting frequency.Lower superheat and higher melting frequency can be used to reduce oxygen content increasing rate. 关 键 词:TIAL合金 真空感应熔炼 氧含量 过热 TIAL基合金 氧化钙坩埚 反应能量 融化时间
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