Novel cobalt(Ⅱ) complexes of amino acids-Schiff bases catalyzed aerobic oxidation of various alcohols to ketones and aldehyde

查看全文 作　　者：Seyed Mohammad [1]Seyedi;Reza [1]Sandaroos;Gholam Hossein [1]Zohuri

机构地区：[1]Department of Chemistry,Faculty of Science,Ferdowsi University of Mashhad

出　　处：《Chinese Chemical Letters》索引2010年第21卷第11期,共4页

摘　　要：Two cobalt(Ⅱ) complexes 1 and 2 of Schiff bases derived from amino acids were synthesized and used for oxidation of benzyl alcohol with molecular oxygen at different conditions of pH,solvent,temperature and complex/alcohol molar ratio to optimize reaction conditions and to evaluate the catalytic efficiency of new cobalt Schiff base complexes.Under obtained optimum conditions,various alcohols were oxidized to corresponding aldehydes and ketones. 关键词：SCHIFF碱配合物催化氧化氨基酸醇酮钴最佳工艺条件醛分子氧氧化

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Novel cobalt(Ⅱ) complexes of amino acids-Schiff bases catalyzed aerobic oxidation of various alcohols to ketones and aldehyde

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