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Molecular Characterization of Hydrotreated Atmospheric Residue Derived from Arabian Heavy Crude by GC FI/FD TOF MS and APPI FT-ICR MS

查看全文 作  者:Diao [1]Rui;Wang [1]Wei;Wang [1]Naixin;Liu [1]Zelong;Dai [1]Lishun;Tian [1]Songbai 高影响力作者 机构地区:[1]Research Institute of Petroleum Processing,SINOPEC高影响力机构 出  处:《China Petroleum Processing & Petrochemical Technology》索引2012年第14卷第4期,共9页高影响力期刊 基  金:supported by the National Basic Research Program of China (2010CB226901) 摘  要:High resolution mass spectrometry in combination with distillation and SARA fractionation provides us an opportunity for in-depth understanding about the hydrotreating process at the molecular level. In this study, the atmospheric residue derived from Arabian heavy crude and its hydrotreated products were initially subjected to distillation and SARA fractionation. The saturates were characterized by GC FI/FD TOF MS. The aromatics and resins were characterized by APPI FT-ICR MS. Compositional changes of different compounds (paraffins, naphthenes, aromatic hydrocarbons, and heteroatomic compounds) contained in different distillates (vacuum gas oil, vacuum residue) were obtained. More detailed knowledge about the hydrotreating process was achieved. 关 键 词:TOF-MS 常压渣油 重质原油 阿拉伯 GC FD 表征 氢分子
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