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Mass production of Li Fe PO_4/C energy materials using Fe–P waste slag

查看全文 作  者:Gen [1]Li;Pengcheng [1]Wu;Chunhui [1]Luo;Qian [1]Cui;Guixin [1]Wang;Kangping [1]Yan 高影响力作者 机构地区:[1]College of Chemical Engineering,Sichuan University高影响力机构 出  处:《Journal of Energy Chemistry》索引2015年第24卷第4期,共6页高影响力期刊 基  金:supported by the National Science Foundation of China(grant no.21206099) 摘  要:To effectively solve the agglomeration problems in the solid state reaction process,pre-adding glucose is adopted to the synthesis of Li Fe PO4/C energy materials using Fe–P waste slag. The average particle & grain size of Li FeP O4/C decreases,and the impurities in Li Fe PO4/C composites reduce to a great extent. It makes great sense to the mass industrial production. The optimum synthesis conditions determined in this work are based on the orthogonal experiments. The samples synthesized in a scale of 500 g exhibit high purity,excellent electrochemical performance,high reaction activity,good reversibility,and low polarization level.The discharge capacities are 145,134,117,and 102 m Ah/g at the current densities of 0.1 C,0.2 C,0.5 C and1 C,respectively. This work puts forward a practical suggestion for mass producing environmental benign and low cost Li FeP O4/C as cathode materials of lithium ion batteries. 关 键 词:材料使用 工业生产 磷渣 能源 最佳合成条件 锂离子电池 C/C复合材料
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