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One-pot/three-step synthesis of zinc-blende CdSe/CdS core/shell nanocrystals with thick shells

查看全文 作  者:Yuan Niu Chaodan Pu Runchen Lai Renyang Meng Wanzhen Lin Haiyan Qin Xiaogang [1]Peng 高影响力作者 机构地区:[1]Center for Chemistry of Novel and High-Performance Materials, and Department of Chemistry, Zhejiang University, Hangzhou 310027, China高影响力机构 出  处:《Nano Research》索引2017年第10卷第4期,共14页高影响力期刊 基  金:Acknowledgements The financial support from the National Natural Science Foundation of China (Nos. 21233005 and 91433204) is acknowledged. 摘  要:A one-pot/three-step synthetic scheme was developed for phase-pure epitaxy of CdS shells on zinc-blende CdSe nanocrystals to yield shells with up to sixteen monolayers. The key parameters for the epitaxy were identified, including the core nanocrystal concentration, solvent type/composition, quality of the core nanocrystals, epitaxial growth temperature, type/concentration of ligands, and composition of the precursors. Most of these key parameters were not influential when the synthetic goal was thin-shell CdSe/CdS core/shell nanocrystals. The finalized synthetic scheme was reproducible at an almost quantitative level in terms of the crystal structure, shell thickness, and optical properties. 关 键 词:ZINC-BLENDE core/shell quantum dots thick shells
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