Effect of Ce doping into V_(2)O_(5)-WO_(3)/TiO_(2) catalysts on the selective catalytic reduction of NO_(x) by NH_(3)

查看全文 作　　者：Mengyin [1]Chen;Mengmeng [1]Zhao;Fushun [1]Tang;Le [1]Ruan;Hongbin [2]Yang;Ning [1]Li

机构地区：[1]College of Chemistry and Bioengineering,Guilin University of Technology,Collaborative Innovation Center for Exploration of Hidden Nonferrous Metal Deposits,Development of New Materials in Guangxi;[2]Guangxi Solid Waste Management Center

出　　处：《Journal of Rare Earths》索引2017年第35卷第12期,共10页

基　　金：Project supported by the Guangxi Natural Science Foundation(2014GXNSFAA118057);Guangxi Science and Technology Planning Project(AB16380276) 摘　　要：In this work, the effectiveness of V_2O_5-WO_3/TiO_2 catalysts modified with different CeO_2 contents by impregnation and co-precipitation methods on the selective catalytic reduction of NOxby NH3 have been studied comparatively by various experimental techniques. The results showed that the NO conversion of V_2O_5-WO_3/CeO_2-TiO_2 catalysts modified by co-precipitation method obviously increased with the Ce doping contents in the studied range below 20%(All Ce contents are in mass fractions), but the NO conversion of V_2O_5-WO_3/CeO_2/TiO_2 catalysts modified by impregnation methods was lower than V_2O_5-WO_3/CeO_2-TiO_2 catalysts especially beyond 2.5% Ce doping contents. The V_2O_5-WO_3/CeO_2-TiO_2 catalysts showed better SCR activity, wider reaction window, and higher sulfur and water resistance. The characterization results elucidated that the modified catalysts by co-precipitation method exhibited higher specific surface area, much better dispersity of Ce component, more Ce^(3+)species and more Br?nsted acid sites than that by impregnation. The vacancies caused by more Ce^(3+)species were favorable for more NO oxidation to NO_2, and the interaction between Ce species and WOxspecies generated more Br?nsted acid sites. It could be supposed that dispersed Ce Oxspecies and WOxspecies offered more second active centers respectively to adsorb oxygen and activate ammonia as co-catalysis to the primary active center of V ions, thus facilitated the better SCR activity of modified V_2O_5-WO_3/CeO_2-TiO_2 catalysts by coprecipitation methods. The co-precipitation methods with Ce component were more suitable for production of modified commercial V_2O_5-WO_3/TiO_2 catalysts. 关键词：V_(2)O_(5)-WO_(3)/TiO_(2) catalysts Ce doping methods NH_(3) selective catalytic reduction NOx Dispersion state Reducibility Bronsted acid sites

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Effect of Ce doping into V_(2)O_(5)-WO_(3)/TiO_(2) catalysts on the selective catalytic reduction of NO_(x) by NH_(3)

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