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Synergistic improvement of perovskite film quality for efficient solar cells via multiple chloride salt additives

查看全文 作  者:Pengyang [1,2]Wang;Qi [1,2]Jiang;Yang [1,2]Zhao;Yong [1,2]Chen;Zema [2]Chu;Xingwang [1,2]Zhang;Yuqin [1]Zhou;Jingbi [1,2]You 高影响力作者 机构地区:[1]College of Materials Science and Opto-electronic Technology, University of Chinese Academy of Sciences;[2]Key Laboratory of Semiconductor Materials Science, Institute of Semiconductors, Chinese Academy of Sciences高影响力机构 出  处:《Science Bulletin》索引2018年第63卷第11期,共6页高影响力期刊 基  金:supported by National 1000 Young Talents Awards;National Key Research and Development Program of China(2016YFB0700700);National Natural Science Foundation of China(61634001,61574133);supported by Hanergy Group 摘  要:Perovskite crystal film quality is critical for obtaining efficient perovskite solar cells. Anti-solvent processing was used for fast crystallization of perovskite precursor film, which can form dense perovskite film.However, the crystals from this method are usually small due to the fast crystal growth process, which could lead to grain boundary recombination. Here, element chloride is introduced to enhance the perovskite layer crystallinity via slowing down the perovskite crystallization process by simultaneous introduction of methylammounium chloride(MACl) and cesium chloride(CsCl) into precursor solution.As a result, we achieve high quality of pin-hole free perovskite film with large crystal size. A power conversion efficiency of 21.55% with free of hysteresis of the device is obtained, which is among the highest efficiency of planar structure perovskite solar cells. 关 键 词:太阳能电池 氯化物 电影 质量 添加剂 多重 生长过程 晶化过程
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