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Remediation of Organochlorine Pesticide-Contaminated Soils by Surfactant-Enhanced Washing Combined with Activated Carbon Selective Adsorption

查看全文 作  者:ZHANG [1,2]Shengtian;HE [2]Yue;WU [3]Linna;WAN [2]Jinzhong;YE [4]Mao;LONG [2]Tao;YAN [2]Zhou;JIANG [2]Xin;LIN [3]Yusuo;LU [3]Xiaohua 高影响力作者 机构地区:[1]College of Resources and Environmental Sciences, Nanjing Agricultural University, Nanjing 210095 (China);[2]State Environmental Protection Key Laboratory of Soil Environmental Management and Pollution Control, Nanjing Institute of Environmental Science, Ministry of Environmental Protection of China, Nanjing 210042 (China);[3]Environmental Science Research Institute, Huazhong University of Science and Technology, Wuhan 430074 (China);[4]State Key Laboratory of Soil and Sustainable Agriculture, Institute of Soil Science, Chinese Academy of Sciences, Nanjing 210008 (China)高影响力机构 出  处:《Pedosphere》索引2019年第29卷第3期,共9页高影响力期刊 基  金:supported by the National Natural Science Foundation of China (Nos. 41571316, 41201311, and 41301278);the Environmental Protection Scientific Research Subject of Jiangsu Province, China (No. 2013026);the National High Technology Research and Development Program (863 Program) of China (No. 2009AA063103) 摘  要:Remediation of organochlorine pesticide (OCP)-contaminated soils is urgently required especially in China. The present study investigated the removal of OCPs from two soils by triton X-100 (TX- 100)-enhanced washing coupled with powdered activated carbon (PAC) adsorption treatment of the solution. Two contaminated soils, including a silt clay contaminated w计h chlordene, dichloro- 2,2-6is(p-chlorophenyl)ethanes (DDDs), and dichlorodiphenyltrichloroethane (DDT) and a sandy loam containing chlordanes and mirex, were selected. Effects of varied operating parameters, including TX-100 dosage, liquid/soil (L/S) ratio, and extraction time, on the contaminant removal were examined. For both soils, OCP removal was clearly enhanced with increasing TX-100 in extraction solution and L/S ratio. Meanwhile, the removal efficacy was also impacted by soil texture and characteristics and contents of the contaminants. Moreover, by using PAC as an absorbent, a significant decrease in the contaminants in the extraction solutions was detected, and TX-100 could be further reused. Our investigation suggests that surfactant-enhanced washing combined with activated carbon selective adsorption would be an alternative to remediate OCP-contaminated soils. 关 键 词:chlordene DICHLORODIPHENYLTRICHLOROETHANE hydrophobic organic chemicals powdered activated carbon sodium dodecyl benzene SULFONATE TRITON X-100
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