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Large-scale fabrication of re duce d graphene oxide-sulfur composite films for flexible lithium-sulfur batteries

查看全文 作  者:Yue [1]Liu;Minjie [1]Yao;Linlin [1]Zhang;Zhiqiang [1]Niu 高影响力作者 机构地区:[1]Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Center, College of Chemistry, Nankai University高影响力机构 出  处:《Journal of Energy Chemistry》索引2019年第28卷第11期,共8页高影响力期刊 基  金:supported by the National Natural Science Foundation of China(21573116 , 51822205 , 21875121 and 51602218);Ministry of Science and Technology of China(2017YFA0206701);Ministry of Education of China(B12015);the Young Thousand Talents Program 摘  要:The rapid development of flexible electronic devices requires the design of flexible energy-storage devices. Lithium-sulfur(Li-S) batteries are attracting much interest due to their high energy density. Therefore, flexible Li-S batteries with high areal capacity are desired. Herein, we fabricated freestanding reduced graphene oxide-sulfur(RGO@S) composite films with a cross-linked structure using a blade coating technique, followed by a subsequent chemical reduction. The porous cross-linked structure endows the composite films with excellent electrochemical performance. The batteries based on RGO@S composite films could exhibit a high discharge capacity of 1381 m Ah/g at 0.1 C and excellent cycle stability. Furthermore, the freestanding composite film possesses excellent conductivity and high mechanical strength. Therefore, they can be used as the cathodes of flexible Li-S batteries. As a proof of concept, soft-packaged Li-S batteries were assembled and remained stable electrochemical performance under different bending states. 关 键 词:Graphene SCALEUP Composite film FLEXIBLE Lithium-sulfur battery
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