Electrochemistry Enabling Stereoselective Diamination of Alkenes

查看全文 作　　者：ZENG [1]Chengchu 机构地区：[1]College of Life Science&Bioengineering,Beijing University of Technology,Beijing 100124,P.R.China 出　　处：《Chemical Research in Chinese Universities》索引2020年第36卷第1期,共2页 摘　　要：To achieve the stereoselective and regioselective diamination of alkenes,Xu et al.developed an electrochemical protocol for the diamination of aryl alkenes with sulfamides by using triarylamine as a redox mediator.The chemistry proceeded in an undivided cell under constant current conditions,featuring not only wide scope of substrates and reasonable yields,but also excellent diastereoselectivity(>20:1 dr)and regioselectivity.This work has been published in the Nature Communications and can be reached at http://gffzzd3cc09b8251d45dfs9o5nuo9ufonb6pov.ffgz.tsg.suse.edu.cn/10.1038/s41467-019-13024-5. 关 键 词：ALKENES proceed redox