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One-step synthesis of biomass derived O, N-codoped hierarchical porous carbon with high surface area for supercapacitors

查看全文 作  者:Shuxian [1]Sun;Fuqin [1]Han;Xiaoliang [1]Wu;Zhuangjun [2]Fan 高影响力作者 机构地区:[1]College of Chemistry,Chemical Engineering and Resource Utilization,Northeast Forestry University,Harbin 150040,China;[2]College of Material Science and Engineering,China University of Petroleum,Qingdao 266580,China高影响力机构 出  处:《Chinese Chemical Letters》索引2020年第31卷第9期,共4页高影响力期刊 基  金:financial support of the National Natural Science Foundation of China(Nos.51702043,51672055 and 51972342);Heilongjiang Postdoctoral Foundation(No.LBH-Z18008)。 摘  要:We report a convenient method to synthesize O,N-codoped hierarchical porous carbon by one-step carbonization of the mixture of KHCO3,urea and alginic acid.Benefiting from KHCO3 and urea syne rgistic effect,the obtained O,N-codoped hierarchical porous carbon(NPC-700) material has a well-developed interconnected porous framework with ultrahigh specific surface area(2846 m2/g) and massive heteroatoms functional groups.Consequence,such porous carbon displays high specific capacitance(324 F/g at 1 A/g),excellent rate performance(212 F/g at 30 A/g) and good electrochemical stabilization in 6 mol/L KOH solution.More importantly,the assembled NPC-700//NPC-700 symmetrical supercapacitor can achieve a high energy density of 18.8 Wh/kg and good electrochemical stabilization in 1 mol/L Na2SO4 solution.This process opens up a new way to design heteroatoms-doped hierarchical porous carbon derived from biomass materials for supercapacitors. 关 键 词:Alginic acid UREA KHCO3 SUPERCAPACITORS Hierarchical porous carbon
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