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Synthesis of highly-branched Au@AgPd core/shell nanoflowers for in situ SERS monitoring of catalytic reactions

查看全文 作　　者：Yujian [1,2]Lai;Lijie [1,2]Dong;Rui [1]Liu;Shaoyu [1,2]Lu;Zuoliang [1,2]He;Wanyu [1,2]Shan;Fanglan [1]Geng;Yaqi [1,2]Cai;Jingfu [1,2,3]Liu 高影响力作者 机构地区：[1]State Key Laboratory of Environmental Chemistry and Ecotoxicology,Research Center for Eco-Environmental Sciences,Chinese Academy of Sciences,Beijing 100085,China;[2]University of Chinese Academy of Sciences,Beijing 100049,China;[3]School of Environment,Hangzhou Institute for Advanced Study,University of Chinese Academy of Sciences,Hangzhou 310024,China高影响力机构 出　　处：《Chinese Chemical Letters》索引2020年第31卷第9期,共5页高影响力期刊 基　　金：supported by the National Key R&D Program of China(No.2016YFA0203102);the National Natural Science Foundation of China(Nos.21620102008 and 21827815)。 摘　　要：Alloy and small size nanostructure s are favorable to catalytical performance,but not to surface-enhanced Raman spectroscopy(SERS) applications.Integrating SERS and catalytic activity into the nanocrystals with both alloy and small size structures is of great interest in fabrication of SERS platform to in situ monitor catalytical reaction.Herein,we report a facile method to synthesize Au@AgPd trimetallic nanoflowers(Au@AgPd NFs) with both SERS and catalytic activities,through simultaneous selective growth of Ag and Pd on Au core to form highly-branched alloy shell.These nanocrystals have the properties of small sizes,defects abundance,and highly-dispersed alloy shell which offer superior catalytic activity,while the merits of monodisperse,excellent stability,and highly-branched shell and core/alloy-shell structure promise the enhanced SERS activity.We further studied their growth mechanisms,and found that the ratio of Ag to Pd,sizes of Au core,and surfactant cetyltrimethylammonium bromide together determine this special structure.Using this as-synthesized nanocrystals,a monolayer bifunctional platform with both SERS and catalytical activity was fabricated through selfassembly at air/water interface,and applied to in situ SERS monitoring the reaction process of Pdcatalyzed hydrogenation of 4-nitrothiophenol to 4-aminothio p henol. 关 键 词：Nanoflower SERS Bifunctional platform AgPd alloy Growth mechanism
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