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Aluminum hydride for solid-state hydrogen storage:Structure,synthesis, thermodynamics, kinetics, and regeneration

查看全文 作  者:Haizhen [1]Liu;Longfei [1]Zhang;Hongyu [1]Ma;Chenglin [1]Lu;Hui [1]Luo;Xinhua [2]Wang;Xiantun [3]Huang;Zhiqiang [1]Lan;Jin [1]Guo 高影响力作者 机构地区:[1]Guangxi Novel Battery Materials Research Center of Engineering Technology,Guangxi Key Laboratory of Processing for Non-ferrous Metallic and Featured Materials,Guangxi Colleges and Universities Key Laboratory of Novel Energy Materials and Related Technology,School of Physical Science and Technology,Guangxi University,Nanning 530004,Guangxi,China;[2]State Key Laboratory of Silicon Materials,School of Materials Science&Engineering,Zhejiang University,Hangzhou 310027,Zhejiang,China;[3]Department of Materials Science and Engineering,Baise College,Baise 533000,Guangxi,China高影响力机构 出  处:《Journal of Energy Chemistry》索引2021年第30卷第1期,共14页高影响力期刊 基  金:financially supported by the National Natural Science Foundation of China (No. 51771171, and 51971199);Education Department of Guangxi Zhuang Autonomous Region (No. 2019KY0021);the Natural Science Foundation of Guangxi Province (2019GXNSFBA185004, and 2018GXNSFAA281308)。 摘  要:Aluminum hydride(AlH3) is a binary metal hydride that contains more than 10.1 wt% of hydrogen and possesses a high volumetric hydrogen density of 148 kg H2 m^(-3).Pristine AlH3 can readily release hydrogen at a moderate temperature below 200℃.Such high hydrogen density and low desorption temperature make AlH3 one of most promising hydrogen storage media for mobile application.This review covers the research activity on the structures,synthesis,decomposition thermodynamics and kinetics,regeneration and application validation of AlH3 over the past decades.Finally,the future research directions of AlH3 as a hydrogen storage material will be revealed. 关 键 词:Hydrogen storage Aluminum hydride AlH3 Research progress Application
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