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A general thermodynamic model for the long-period stacking ordered phases in magnesium alloys

查看全文 作  者:Kai [1,2]Xu;Shuhong [2]Liu;Keke [1]Chang;Yongpeng [2]Liang;Yong [2]Du;Zhanpeng [3]Jin 高影响力作者 机构地区:[1]Key Laboratory of Marine Materials and Related Technologies,Zhejiang Key Laboratory of Marine Materials and Protective Technologies,Ningbo Institute of Materials Technology and Engineering,Chinese Academy of Sciences,Ningbo,Zhejiang 315201,China;[2]Science and Technology on High Strength Structural Materials Laboratory,Central South University,Changsha,Hunan 410083,China;[3]School of Materials Science and Engineering,Central South University,Changsha,Hunan 410083,China高影响力机构 出  处:《Journal of Magnesium and Alloys》索引2021年第9卷第1期,共12页高影响力期刊 基  金:This work was supported by the National Key Research and Development Plan(No.2016YFB0701202).K.Chang ac-knowledges the CAS Pioneer Hundred Talents Program.Pro-fessor Zi-Kui Liu is greatly acknowledged for the discussion about the general thermodynamic model for LPSOs. 摘  要:A thermodynamic model Mg x(Xs,Mg)6(Xl,Mg)8(Xs and Xl are elements smaller and larger than Mg)for long-period stacking ordered phases(LPSOs)was proposed based on two key factors:the Xs 6 Xl 8-type L12 clusters and the variation of chemical compositions.In general,all available LPSOs can be described with this model.As a representative system,Mg-Y-Zn with three LPSOs was investigated using the CALPHAD(calculation of phase diagram)approach aided with first-principles calculations.Two new three-phase equilibria were predicted and were validated by key experiments.The model-based descriptions will be the basis for the research and development of magnesium alloys. 关 键 词:LPSOs Thermodynamic model Formation enthalpy CALPHAD SOLIDIFICATION
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