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Applications of metal-organic framework composites in CO_(2) capture and conversion

查看全文 作  者:Jiewei [1,2,4]Liu;Chunying [3]Chen;Kun [1]Zhang;Li [3]Zhang 高影响力作者 机构地区:[1]School of Biotechnology and Health Sciences,Wuyi University.Jiangmen 529020,China;[2]International Healthcare Innovation Institute(Jiangmen),Jiangmen 529040,China;[3]School of Chemistry,Sun Yat-sen University,Guangzhou 510275,China;[4]School of Chemical Engineering and Light Industry,Guangdong University of Technology.Guangzhou 510006,China高影响力机构 出  处:《Chinese Chemical Letters》索引2021年第32卷第2期,共11页高影响力期刊 基  金:the support from the National Natural Science Foundation of China (Nos.21773314, 21720102007,21821003 and 21890382);the Guangdong Natural Science Funds for Distinguished Young Scholar (No. 2019B151502017);the Tip-top Youth Talents of Guangdong special support program (No.20173100042150021);Science and Technology Planning Project of Guangzhou (No.201707010168);the General Financial Grant from the China Postdoctoral Science Foundation (No.2019M662809);Local Innovative and Research Teams Project of Guangdong Peal River Talents Program (No.2017BT01C161)。 摘  要:Reliable technologies for CO_(2) capture and conversion(C3) are of vital importance for the establishment of a sustainable society.Metal-organic framework(MOF) composites have shown their compelling potentials for C3 due to the plentiful reticular chemistry of MOF structures and the synergistic catalysis between MOFs and the functional guests.This review focuses on the syntheses and catalytic applications towards C3 of MOF composites,which is divided into three sections.The first section gives a brief introduction about synthetic strategies of MOF composites.The second section discusses the recent progress of MOF composites in C3,including CO_(2) chemical fixation,hydrogenation,photoreduction,electro reduction and photoelectro reduction.The third section summarizes the challenges and future prospects of MOF composites for C3.We hope that this review cannot only provide an inspiration for the rational design of MOF composites for C3,but also stimulate more and more research works in this emerging area. 关 键 词:Metal-organic framework composites CO_(2)chemical fixation CO_(2)hydrogenation CO_(2)photoreduction CO_(2)electroreduction CO_(2)photoelectroreduction
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