A Top-Down Approach towards Cu(I)Alkynyl Clusters with Unusual Geometry

查看全文 作　　者：Huan [1]Li;Ting [1,2]Li;Shuimiao [1]Liu;Mei [1,2]Qu;Linfeng [1]Liang;Fengwei [1]Zhang;Xian-Ming [1,2]Zhang

机构地区：[1]Institute of Crystalline Materials,Shanxi University,Taiyuan,Shanxi,030006 China;[2]School of Chemistry and Material Science,Shanxi Normal University,Linfen,Shanxi,041004 China

出　　处：《Chinese Journal of Chemistry》索引2021年第39卷第4期,共5页

基　　金：the National Natural Science Foundation of China(Nos.21972080,21503123,91961201,21871167);1331 project for Featured Chemistry Discipline in Shanxi Normal University. 摘　　要：Main observation and conclusion To search for novel Cu(I)complexes,traditional approaches focus on designing and screening ligands,metal precursors and reaction parameters.In this report,we propose a top-down approach,in which Cu precursor is first reduced to nanoparticles in the presence of alkynyl and phosphine ligands. 关键词：Copper TOP-DOWN Cluster Fluorescence ALKYNYL

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A Top-Down Approach towards Cu(I)Alkynyl Clusters with Unusual Geometry

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