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Mixed polyanion cathode materials:Toward stable and high-energy sodium-ion batteries

查看全文 作  者:Along [1]Zhao;Yongjin [1]Fang;Xinping [1]Ai;Hanxi [1]Yang;Yuliang [1]Cao 高影响力作者 机构地区:[1]Engineering Research Center of Organosilicon Compounds and Materials of Ministry of Education,College of Chemistry and Molecular Sciences,Wuhan University,Wuhan 430072,Hubei,China高影响力机构 出  处:《Journal of Energy Chemistry》索引2021年第30卷第9期,共14页高影响力期刊 基  金:financial support by the National Science Foundation of China(Nos.21673165 and 21972108);the National Key Research Program of China(No.2016YFB0901500);the supercomputing system in the Supercomputing Center of Wuhan University。 摘  要:Sodium-ion batteries(SIBs)are considered as one of the most fascinating alternatives to lithium-ion batteries for grid-scale energy storage applications because of the low cost and wide abundance of sodium resources.Among various cathode materials,mixed polyanion compounds come into the spotlight as promising electrode materials due to their superior electrochemical properties,such as high working voltage,long cycling stability,and facile reaction kinetics.In this review,we summarize the recent development in the exploration of different mixed polyanion cathode materials for SIBs.We provide a comprehensive understanding of the structure-composition-performance relationship of mixed polyanion cathode materials together with the discussion of their sodium storage mechanisms.It is anticipated that further innovative works on the material design of advanced cathode materials for batteries can be inspired. 关 键 词:Mixed polyanion compounds Cathode materials POLYANIONS Energy storage Sodium-ion batteries
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