Spin switching in corrole radical complex

查看全文 作　　者：Chunyan [1,2]Yu;Hongping [2]Xiao;Hua [1]Lu;Yongshu [3]Xie 机构地区：[1]College of Material,Chemistry and Chemical Engineering,Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education,Hangzhou Normal University,Hangzhou 311121,China;[2]College of Chemistry and Materials Engineering,Wenzhou University,Wenzhou 325035,China;[3]Functional Materials Chemistry,Key Laboratory for Advanced Materials and Institute of Fine Chemicals,School of Chemistry&Molecular Engineering,East China University of Science&Technology,Shanghai 200237,China 出　　处：《Chinese Chemical Letters》索引2024年第35卷第1期,共2页 摘　　要：Spintronics is a cutting-edge field of developing new electronic devices by manipulating the electron spin and magnetic moment[1].Traditional spintronic research mainly focuses on transition metals and inorganic semiconductors,while organic molecules have the advantage of being extremely easy to realize efficient spin control by modifying the specific external conditions for desired electronic structures and magnetic characteristics.Corrole,as a ring-contracted porphyrin,is the aromatic analog of the central macrocycle of vitamin Bi2.Corrole has a squeezed inner cavity and three inner NHs in its free-base form,making it easier to stabilize high-valent metal ions and thus a promising candidate in spintronics. 关 键 词：CORROLE INNER RADICAL