Recent progress in ternary mixed matrix membranes for CO_(2) separation

查看全文 作　　者：Zikang [1,2,3,4]Qin;Yulei [1,2,3,4]Ma;Jing [1,2,3,4]Wei;Hongfang [1,2,3,4]Guo;Bangda [1,3,4]Wang;Jing [5]Deng;Chunhai [6]Yi;Nanwen [7]Li;Shouliang [8]Yi;Yi [9,10]Deng;Wentao [9,10]Du;Jian [11]Shen;Wenju [1,3,4]Jiang;Lu [1,3,4]Yao;Lin [1,3,4]Yang;Zhongde [1,3,4]Dai

机构地区：[1]College of Architecture and Environment,Sichuan University,Chengdu,610065,China;[2]College of Carbon Neutrality Future Technology,Sichuan University,Chengdu,610065,China;[3]National Engineering Research Centre for Flue Gas Desulfurization,Chengdu,610065,China;[4]Carbon Neutral Technology Innovation Center of Sichuan,Chengdu,610065,China;[5]School of Chemical,Biological and Materials Engineering,University of Oklahoma,Norman,OK,73019,USA;[6]Shaanxi Key Laboratory of Energy Chemical Process Intensification,School of Chemical Engineering and Technology,Xi'an Jiaotong University,Xi'an,710049,China;[7]State Key Laboratory of Coal Conversion,Institute of Coal Chemistry,Chinese Academy of Sciences,Taiyuan,030001,China;[8]US DOE,Natl Energy Technol Lab,626 Cochrans Mill Rd,Pittsburgh,PA 15236,USA;[9]DongFang Boiler Co.,Ltd.,China;[10]Clean Combustion and Flue Gas Purification Key Laboratory of Sichuan Province,Chengdu,611731,China;[11]College of Environment and Resources,Xiangtan University,Xiangtan,411105,China

出　　处：《Green Energy & Environment》索引2024年第9卷第5期,共28页

基　　金：support from Sichuan Science and Technology Program(2021YFH0116);National Natural Science Foundation of China(No.52170112);DongFang Boiler Co.,Ltd.(3522015). 摘　　要：Mixed matrix membranes(MMMs)could combine the advantages of both polymeric membranes and porousﬁllers,making them an effective alternative to conventional polymer membranes.However,interfacial incompatibility issues,such as the presence of interfacial voids,hardening of polymer chains,and blockage of micropores by polymers between common MMMsﬁllers and the polymer matrix,currently limit the gas sep-aration performance of MMMs.Ternary phase MMMs(consisting of aﬁller,an additive,and a matrix)made by adding a third compound,usually functionalized additives,can overcome the structural problems of binary phase MMMs and positively impact membrane separation performance.This review introduces the structure and fabrication processes for ternary MMMs,categorizes various nanoﬁllers and the third component,and summarizes and analyzes in detail the CO_(2) separation performance of newly developed ternary MMMs based on both rubbery and glassy polymers.Based on this separation data,the challenges of ternary MMMs are also discussed.Finally,future directions for ternary MMMs are proposed. 关键词：CO_(2)separation Mixed matrix membranes Ternary phase

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Recent progress in ternary mixed matrix membranes for CO_(2) separation

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