SORPTION BEHAVIOR AND MECHANISM OF SAMARIUM(III) ON AMINO METHYLENE PHOSPHONIC ACID RESIN

查看全文 作　　者：Wang Yongjiang WU Xiangmei Xiong Chunhua** Department of Chemistry, Lishui Teachers College, Lishui, Zhejiang 323000 出　　处：《Chinese Journal of Reactive Polymers》索引2001年第10卷第2期,共6页 基　　金：Foundations of Zhejiang Provincial Education Ministry (No.20010677) 摘　　要：Sm(III) was quantitatively adsorbed by amino methylene phosphonic acid resin (APAR) in the medium of pH=5.0. The statically saturated sorption capacity is 251mg/g·resin. Sm(III) adsorbed on APAR can be reductively eluted by 2.0mol/L HCl. The sorption rate constant is k298= 1.35×10-5s-1. The sorption behavior of APAR for Sm(III) obeys the Freundlich isotherm. The enthalpy change △H of sorption is 24.9kJ/mol. The apparent activation energy is Ea=11.7kJ/mol. The sorption mechanism shows that the nitrogen and oxygen atoms of the functional group of APAR coordinated with Sm(III) to form coordination bond. 关 键 词：树脂 钐 吸收性能