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1篇 您的检索式:作者名="Azra Amiri"
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1Determination of captopril in patient human urine using ferrocenemonocarboxylic acid modified carbon nanotubes paste electrode显示文摘In this work,we describe a new strategy for the electrochemical determination of captopril(CA) using ferrocenemonocarboxylic acid as a mediator and multiwall carbon nanotubes as sensors in aqueous solution at pH 7.0.The diffusion coefficient(D),and the kinetic parameters such as electron transfer coefficient(α).and heterogeneous rate constant(k_h),for CA were also determined using electrochemical approaches.Under the optimized conditions,the electrocatalytic oxidation peak current of captopril showed two linear dynamic ranges with a detection limit of 0.3×10^(-6) mol L^(-1) captopril.The linear calibration range was 0.8×10^(-6) to 65×10^(-6) mol L^(-1) using cyclic voltammetry.Finally,this modified electrode was also examined as a selective,simple and precise new electrochemical sensor for the determination of captopril in real samples such as drug and patient human urine.Mohammad A.Khalilzadeh Hassan Karimi-Maleh Azra Amiri Fathali Gholami Robabeh Motaghed Mazhabi 2010Chinese Chemical Letters2010,21,12:2
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