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| 1 | Bioavailability of Arsenic and Antimony in Terrestrial Ecosystems:A Review显示文摘Arsenic (As) and antimony (Sb) are metalloids that belong to group 15 of the periodic table and exhibit toxic properties in the environment. They mostly occur naturally at low concentrations in soil, although these can be significantly elevated in both aquatic and terrestrial food chains as a result of dispersion from anthropogenic sources, e.g ., mining activities. The bioavailability, i.e., the proportion of the contaminant in soil and dust that is available for uptake by plants and other living organisms, presents the greatest risk to terrestrial ecosystems. Various in vivo and in vitro methods have been used to measure As and Sb bioaccessibility in soil and dust. In vivo measurement of bioavailability can be time consuming, expensive, and unethical;thus, in vitro methods are commonly preferred. However, there is considerable uncertainty around the efficacy of in vitro tools used to measure the bioavailable fractions of As and Sb. The results of these methods are dependent on many variables, e.g., soil characteristics, contaminant sources, and chemical composition of in vitro methods. Therefore, substantial variations are observed between in vitro and in vivo results obtained from different test animals and endpoints. In this paper, we review the literature on As and Sb bioavailability in terrestrial ecosystems and current in vivo and in vitro techniques used for assessing bioavailability and bioaccessibility of metalloids. This would reveal research gaps and allow scientists and environmental policy makers to gain a deeper understanding of the potential risks associated with these metalloids in the environment. | Saeed BAGHERIFAM Trevor CBROWN Christopher MFELLOWS Ravi NAIDU | 2019 | Pedosphere2019，29，6： | 6 |
| 2 | Uranium removal fromaqueous solutions by wood powder and wheat straw 显示文摘 | BagherifamS Lakzian A Ahmadi S J | 2010 | Journal ofRadioanalytical and Nuclear Chemistry2010，283，： | 1 |
| 3 | The effect of different uranium concentrations on physiological charac - teristics and chlorophyll contents in sunflowers and soy bean 显示文摘 | Bagherifam S Lakzian A Ahmadi S J | 2009 | Journal of Nuclear Science and Technology2009，40，45： | 1 |
| 4 | Thermal degradation of polysiloxane and polyetherester containing benzoxazine moieties in the main chain显示文摘 | Bagherifam S Kiskan B Aydogan B | 2011 | Journal of Analytical and Applied Pyrolysis2011，90，2： | 1 |
| 5 | In situ stabilization of As and Sb with naturally occurring Mn, Al and Fe oxides in a calcareous soil: Bioaccessibility, bioavailability and speciation studies显示文摘 | Saeed Bagherifam Amir Lakzian Amir Fotovat Reza Khorasani Sridhar Komarneni | 2014 | Journal of Hazardous Materials2014，，： | 1 |
| 6 | In situ stabilization of arsenic in soil with organoclay,organozeolite,birnessite,goethite and lanthanum-doped magnetic biochar显示文摘Arsenic(As)is a known carcinogen and naturally occurring semi-metal in soils and in the Earth's crust.Contamination of soils and water with As poses a serious threat to millions of people worldwide due to its health hazards and toxicological properties.Hence,devising novel and efficient methods for remediation of contaminated areas has attracted a great deal of interest across the globe.In this study,we investigated the usefulness of synthetic birnessite,goethite,hexadecylpyridinium chloride-modified montmorillonite(HDPC-M),hexadecylpyridinium bromide-modified zeolite(HDPB-Z),and lanthanum(La)-doped magnetic biochar produced from eucalyptus bark(La-Euchar)as adsorbents at 10%dosage for As stabilization in a soil spiked with 1000 mg kg^(-1)As.The effectiveness of the above adsorbents in As immobilization in soil was assessed using single-step extractions with 2 mol L^(-1)HNO_(3)and deionized water,the simplified bioaccessibility extraction test(SBET)method,and sequential extraction with the modified Community Bureau of Reference(BCR)method.Application of the adsorbents shifted the exchangeable fraction of As to more recalcitrant fractions and dramatically reduced the exchangeable fraction by 6%-99%and the extractable amounts with HNO_(3),deionized water,and SBET method by 30%-92%,17%-95%,and 12%-90%,respectively,compared to the unamended control.The immobilizing effects of adsorbents on As decreased in the sequence of birnessite>La-Euchar>goethite>HDPB-Z>HDPC-M.Birnessite exhibited great affinity for As and drastically reduced As extractability by more than 90%in all single extractions.The results revealed that HDPC-M,HDPB-Z,La-Euchar,birnessite,and goethite are promising immobilizing agents for in situ stabilization of As in terrestrial environments. | Saeed BAGHERIFAM Trevor C.BROWN Christopher M.FELLOWS Ravi NAIDU Sridhar KOMARNENI | 2022 | Pedosphere2022，32，5： | 1 |
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