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| 1 | Synthesis, properties and applications of one- and two- dimensional gold nanostructures显示文摘因为金 nanomaterials 的性质和功能高度依赖于他们的粒子尺寸,形状,和维数,金 nanocrystals 的控制合成是集中的研究的题目十年了。特别,各向异性的金 nanocrystals 例如 nanowires, nanobelts, nanoplates 和 nanosheets,在电子学由于他们的惹人注目的性质和有希望的应用吸引了许多注意,催化作用, photonics,察觉到并且 biomedicine。在这评论,我们将总结 onedimensional (1D ) 的最近的开发并且二维(2D ) 金 nanostructures。为这些 1D 和 2D 金牌 nanocrystals 的准备的合成方法的各种各样的类型将被描述。而且,我们将简短也介绍性质和这些 1D 和 2D 金牌 nanocrystals 的潜在的应用。 | Xun Hong Chaoliang Tan Junze Chen Zhichuan Xu Hua Zhang | 2015 | Nano Research2015，8，1： | 9 |
| 2 | Crystal phase-controlled growth of PtCu and PtCo alloys on 4H Au nanoribbons for electrocatalytic ethanol oxidation reaction显示文摘Crystal phase can greatly affect the physicochemical properties and applications of nanomaterials.However,it stil remains a great challenge to synthesize nanostructures with the same composition and morphology but different phases in order to explore the phase-dependent properties and applications.Herein,we report the crystal phase-controlled synthesis of PtCu alloy shells on 4H Au nanoribbons(NRBs),referred to as 4H-Au NRBs,to form the 4H-Au@PtCu core-shell NRBs.By tuning the thickness of PtCu,4H-PtCu and face-centered cubic(cc)phase PICu(cc-PtCu)alloy shells are successtully grown on the 4H-Au NRB cores.This thickness-dependent phase-controlled growth strategy can also be used to grow PtCo alloys with 4H or fcc phase on 4H-Au NRBs.Significantly,when used as electrocatalysts for the ethanol oxidation reaction(EOR)in alkaline media,the 4H-Au@4H-PtCu NRBs show much better EOR performance than the 4H-Au@fcc-PtCu NRBs,and both of them possess superior performance compared to the commercial Pt black.Our study provides a strategy on phase-contolled synthesis of nanomaterials used for crystal phase-dependent applications. | Jie Wang Jian Zhang Guigao Liu Chongyi Ling Bo Chen Jingtao Huang Xiaozhi Liu Bing Li An-Liang Wang Zhaoning Hu Ming Zhou Ye Chen Hongfei Cheng Jiawei Liu Zhanxi Fan Nailiang Yang Chaoliang Tan Lin Gu Jinlan Wang Hua Zhang | 2020 | Nano Research2020，13，7： | 2 |
| 3 | A General Method for the Synthesis of Hybrid Nanostructures Using MoSe_(2) Nanosheet-Assembled Nanospheres as Templates显示文摘The layered transition metal dichalcogenides(TMDs)and transition metal phosphides are low-cost,earth-abundant,and robust electrocatalysts for hydrogen evolution reaction(HER).Integrating them into hybrid nanostructures is potentially promising to further boost the catalytic activity toward HER based on their synergistic effects.Herein,we report a general method for the synthesis of a series of MoSe_(2)-based hybrid nanostructures,including MoSe_(2)-Ni_(2)P,MoSe_(2)-Co_(2)P,MoSe_(2)-Ni,MoSe_(2)-Co,and MoSe_(2)-NiS,by postgrowth of Ni_(2)P,Co_(2)P,Ni,Co,and NiS nanostructures on the presynthesized MoSe_(2) nanosheet-assembled nanospheres,respectively,via a colloidal synthesis method.As a proof-of-concept application,the as-synthesized hybrid nanostructures are used as electrocatalysts for HER,exhibiting high activity and stability in acidic media.Among them,the MoSe_(2)-Co_(2)P composite shows the highest HER activity with an overpotential of 167 mV at 10 mA cm^(-2). | Shikui Han Kai Zhou Yifu Yu Chaoliang Tan Junze Chen Ying Huang Qinglang Ma Ye Chen Hongfei Cheng Weijia Zhou Hua Zhang | 2019 | Research2019，，1： | 1 |
| 4 | Two-dimensional alloyed transition metal dichalcogenide nanosheets:Synthesis and applications显示文摘Two-dimensional(2D)transition metal dichalcogenide(TMD)nanosheets have attracted considerable attention owing to their diverse properties and great potential in a wide range of applications.In order to further tune their properties and then broaden their application domain,large efforts have been devoted into engineering the structures of 2D TMD nanosheets at atomic scale,especially the alloying technology.Alloying different 2D TMD nanosheets into 2D alloys not only offers the opportunities to fine-tune their physical/chemical properties,but also opens up some unique properties,which are highly desirable for wide applications including electronics,optoelectronics and catalysis.This review summarizes the recent progress in the preparation,characterization and applications of 2D alloyed TMD nanosheets. | Haoxin Huang Jiajia Zha Shisheng Li Chaoliang Tan | 2022 | Chinese Chemical Letters2022，33，1： | 1 |
| 5 | Sin- gle-layer transition metal dichalcogenide nanosheet-assis- ted assembly of aggregation-induced emission molecules to form organic nanosheets with enhanced fluorescence显示文摘 | TAN Chaoliang QI Xiaoying HUANG Xiao | 2014 | Adv Mater2014，26，11： | 1 |
| 6 | Graphene-Based E- lectro - chemical Sensors 显示文摘 | Shixin Wu Qiyuan He Chaoliang Tan Ya- dong Wang Hua Zhang | 2013 | Small2013，，： | 1 |
| 7 | Size engineering of 2D MOF nanosheets for enhanced photodynamic antimicrobial therapy显示文摘Although porphyrin-based metal-organic frameworks(MOFs)have been widely explored as photosensitizers for photodynamic therapy,how the size will affect the light-induced catalytic activity for generation of reactive oxygen species(ROS)still remain unclear.Herein,we first report the size-controlled synthesis of two-dimensional(2D)porphyrin-based PCN-134 MOF nanosheets by a two-step solvothermal method to explore the size effect on its PDT performance,thus yielding enhanced photodynamic antimicrobial therapy.By simply controlling the reaction temperature in the synthesis process,the bulk PCN-134 crystal,large PCN-134(L-PCN-134)nanosheets with a lateral size of 2–3μm and thickness of 33.2–37.5 nm and small PCN-134 nanosheets(S-PCN-134)with a lateral size of 160–180 nm and thickness of 9.1–9.7 nm were successfully prepared.Interestingly,the S-PCN-134 nanosheets exhibit much higher photodynamic activity for ROS generation than that of the bulk 3D PCN-134 crystal and L-PCN-134 nanosheets under a660 nm laser irradiation,suggesting that the photodynamic activity of PCN-134 MOF increases when the size reduces.Therefore,the S-PCN-134 nanosheets show much enhanced performance when used as a photosensitizer for photodynamic antimicrobial activity and wound healing. | Baoli Xue Xiwen Geng Haohao Cui Huiying Chen Zhikang Wu Hong Chen Hai Li Zhan Zhou Meiting Zhao Chaoliang Tan Jingguo Li | 2023 | Chinese Chemical Letters2023，34，9： | 0 |
| 8 | Activating MoO_(3) nanobelts via aqueous intercalation as a near-infrared type I photosensitizer for photodynamic periodontitis treatment显示文摘Although molybdenum trioxide nanomaterials have been widely explored as nanoagents for biomedical applications against bacteria through photothermal therapy,chemodynamic therapy,and catalytic therapy,their utilization as photosensitizers for photodynamic therapy(PDT)have been rarely reported so far.Herein,we report the activation of MoO_(3) nanobelts via aqueous co-intercalation of Na+and H_(2)O into their van der Waals gaps as a near-infrared Type I photosensitizer for photodynamic periodontitis treatment.The Na^(+)/H_(2)O intercalation of MoO_(3) nanobelts can shorten its length,generate rich oxygen vacancies,and enlarge its interlayer gaps.Such structural changes thus can induce the color change from white to dark blue with a strong near-infrared(NIR)absorption.When used as a photosensitizer,the I-MoO_(3−x) nanobelts exhibit much higher activities for the generation of superoxide radical(·O_(2)^(−))under an 808 nm laser irradiation than that of the pristine MoO_(3) nanobelts.Therefore,the prepared I-MoO_(3)−x nanobelts show a spectral antibacterial activity against Escherichia coli and Saccharomyces aureus,thus yielding a good clinical therapeutic effect on periodontitis.Our study proves that aqueous intercalation can be a simple but powerful strategy to activate layered MoO_(3) nanomaterials for high-performance PDT. | Bohua Li Dandan Chu Haohao Cui Zhanrong Li Zhan Zhou Chaoliang Tan Jingguo Li | 2023 | SmartMat2023，4，6： | 0 |
| 9 | Growth of Tellurium Nanobelts on h-BN for p-type Transistors with Ultrahigh Hole Mobility显示文摘The lack of stable p-type van der Waals(vdW)semiconductors with high hole mobility severely impedes the step of low-dimensional materials entering the industrial circle.Although p-type black phosphorus(bP)and tellurium(Te)have shown promising hole mobilities,the instability under ambient conditions of bP and relatively low hole mobility of Te remain as daunting issues.Here we report the growth of high-quality Te nanobelts on atomically flat hexagonal boron nitride(h-BN)for high-performance p-type field-effect transistors(FETs).Importantly,the Te-based FET exhibits an ultrahigh hole mobility up to 1370 cm^(2) V^(−1) s^(−1) at room temperature,that may lay the foundation for the future high-performance p-type 2D FET and metal-oxide-semiconductor(p-MOS)inverter.The vdW h-BN dielectric substrate not only provides an ultra-flat surface without dangling bonds for growth of high-quality Te nanobelts,but also reduces the scattering centers at the interface between the channel material and the dielectric layer,thus resulting in the ultrahigh hole mobility. | Peng Yang Jiajia Zha Guoyun Gao Long Zheng Haoxin Huang Yunpeng Xia Songcen Xu Tengfei Xiong Zhuomin Zhang Zhengbao Yang Ye Chen Dong-Keun Ki Juin J.Liou Wugang Liao Chaoliang Tan | 2022 | Nano-Micro Letters2022，14，7： | 0 |
| 10 | Recent advances in two-dimensional nanomaterials for bone tissue engineering显示文摘Over the last decades,bone tissue engineering has increasingly become a research focus in the field of biomedical engineering,in which biomaterials play an important role because they can provide both biomechanical support and osteogenic microenvironment in the process of bone regeneration.Among these biomaterials,two-dimensional(2D)nanomaterials have recently attracted considerable interest owing to their fantastic physicochemical and biological properties including great biocompatibility,excellent osteogenic capability,large specific surface area,and outstanding drug loading capacity.In this review,we summarize the state-of-the-art advances in 2D nanomaterials for bone tissue engineering.Firstly,we introduce the most explored biomaterials used in bone tissue engineering and their advantages.We then highlight the advances of cutting-edge 2D nanomaterials such as graphene and its derivatives,layered double hydroxides,black phosphorus,transition metal dichalcogenides,montmorillonite,hexagonal boron nitride,graphite phase carbon nitride,and transition metal carbonitrides(MXenes)used in bone tissue engineering.Finally,the current challenges and future prospects of 2D nanomaterials for bone tissue regeneration in process of clinical translation are discussed. | Zhiquan Cao Yixin Bian Tingting Hu Yu Yang Zhuolin Cui Tao Wang Shuqing Yang Xisheng Weng Ruizheng Liang Chaoliang Tan | 2023 | Journal of Materiomics2023，9，5： | 0 |
| 11 | A universal method for rapid and large‐scale growth of layered crystals显示文摘Layered van der Waals(vdW)materials,consisting of atomically thin layers,are of paramount importance in physics,chemistry,and materials science owing to their unique properties and various promising applications.However,their fast and large‐scale growth via a general approach is still a big challenge,severely limiting their practical implementations.Here,we report a universal method for rapid(~60 min)and large‐scale(gram scale)growth of phase‐pure,high‐crystalline layered vdW materials from their elementary powders via microwave plasma heating in sealed ampoules.This method can be used for growth of 30 compounds with different components(binary,ternary,and quaternary)and properties.The ferroelectric and transport properties of mechanically exfoliated flakes validate the high crystal quality of the grown materials.Our study provides a general strategy for the fast and large‐scale growth of layered vdW materials with appealing physiochemical properties,which could be used for various promising applications. | Apoorva Chaturvedi Bo Chen Keke Zhang Qiyuan He Gwang‐Hyeon Nam Lu You Zhuangchai Lai Chaoliang Tan Thu Ha Tran Guigao Liu Jiadong Zhou Zheng Liu Junling Wang Edwin H.T.Teo Hua Zhang | 2020 | SmartMat2020，1，1： | 0 |
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