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您的检索式：作者名="Chengxing Cui"
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| 1 | Ionic liquids-SBA-15 hybrid catalysts for highly efficient and solvent-free synthesis of diphenyl carbonate显示文摘Diphenyl carbonate(DPC)is one of the versatile carbonates,and is often used for the production of polycarbonates.In recent years,the catalytic synthesis of DPC has become an important topic but the development of a highly active metal-free catalyst is a great challenge.Herein,a series of ionic liquids-SBA-15 hybrid catalysts with different functional groups have been developed for the synthesis of DPC under solventfree condition,which are effective and clean instead of the metal-containing catalysts.It is found that in the presence of[SBA-15-IL-OH]Br catalyst,methyl phenyl carbonate(MPC)conversion of 80.5%along with 99.6%DPC selectivity is achieved,the TOF value is thrice higher than the best value reported by using transition metal-based catalysts.Moreover,the catalyst displays remarkable stability and recyclability.This work provides a new idea to design and prepare eco-friendly catalysts in a broad range of applications for the green synthesis of carbonates. | Songlin Wang Qiying Zhang Chengxing Cui Hongying Niu Cailing Wu Jianji Wang | 2023 | Green Energy & Environment2023，8，1： | 1 |
| 2 | Regio-and Stereoselective Synthesis of(Z)-3-Ylidenephthalides via H_(3)PMo1_(2)O_(40)-Catalyzed Cyclization of 2-Acylbenzoic Acids with Benzylic Alcohols显示文摘We report an exclusively tandem C—O and C—C bond forming beyond the esterification and cyclization reaction of 2-acylbenzoic acids with alcohols to regio-and stereoselective synthesis of the(Z)-3-ylidenephthalides.The reaction uses the nontoxic,inexpensive H_(3)PMo1_(2)O_(40) as catalyst and produces water as the sole by-product,making the reaction environmentally benign and sustainable.Moreover,this reaction features an eco-friendly reaction condition,facile scalability,and easy derivatization of the products to drugs and bioactive compounds.The mechanism studies and density functional theory calculations reveal that the appropriate acid catalyst is the key to the selectivity of this transformation. | Guoping Yang Ke Li Xiaoling Lin Yijin Li Chengxing Cui Shixiong Li Yuanyuan Cheng Yufeng Liu | 2021 | Chinese Journal of Chemistry2021，39，11： | 1 |
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