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您的检索式：作者名="DAVID P.CANN"
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| 1 | DIELECTRIC AND PIEZOELECTRIC PROPERTIES OF(K,Na)NbO_(3)-BASED PIEZOELECTRIC CERAMICS显示文摘Solid solutions based on Li,Ta and Sb-doped(K_(0.5)Na_(0.5))NbO_(3)(KNN)lead-free perovskite systems were created using standard solid-state methods.X-ray diffraction was used to conrm that all compositions were single phase and to verify the phase transition from tetragonal to cubic at T_(C)=302℃.The three compositions examined,originally developed by Saito and Li,were shown to be strongly ferroelectric with sharp peaks in permittivity present at the Curie temperature.The optimum composition had loss tangent values below 5%up to 100 kHz at room temperature.Bipolar hysteresis measurements showed high values for both maximum polarization(25 and 21μC/cm^(2))and remenant polarizations(20 and 16μC/cm^(2))for undoped and 0.2 wt%CuO-doped samples.Maximum strain values of greater than 0.23%were observed. | ERIC A.PATTERSON DAVID P.CANN | 2011 | Journal of Advanced Dielectrics2011，1，3： | 0 |
| 2 | Dual-shell silicate and alumina coating for long lasting and high capacity lithium ion batteries显示文摘Here we demonstrate a theory-driven, novel dual-shell coating system of Li_(2)SrSiO_(4) and Al_(2)O_(3), achieved via a facile and scalable sol-gel technique on LiCoO_(2) electrode particles. The optimal thickness of each coating can lead to increased specific capacity(~185 m Ah/g at 0.5 C-rate) at a cut-off potential of 4.5 V, and greater cycling stability at very high C rates(up to 10 C) in half-cells with lithium metal. The mechanism of this superior performance was investigated using a combination of X-ray and electron characterization methods. It shows that the results of this investigation can inform future studies to identify still better dual-shell coating schemes, achieved by such industrially feasible techniques, for application on similar, nickel-rich cathode materials. | Marcos Lucero Tucker M.Holstun Yudong Yao Ryan Faase Maoyu Wang Alpha T.N’Diaye David P.Cann Joe Baio Junjing Deng Zhenxing Feng | 2022 | Journal of Energy Chemistry2022，31，5： | 0 |
| 3 | Effects of A-site nonstoichiometry on oxide ion conduction in 0.94Bi_(0.5)Na_(0.5)TiO_(3)-0.06BaTiO_(3) ceramics显示文摘Lead free 0.94(Bi_(0.5)Na_(0.5))TiO_(3)-0.06BaTiO_(3)ceramics were prepared by conventional solid-state mixed oxide route with the A-site stoichiometry modified to incorporate donor-doping(through Bi-excess)and acceptor-doping(through Na-excess).Both stoichiometric and nonstoichiometric ceramics exhibited a single perovskite phase with pseudo-cubic symmetry.A significant improvement in the dielectric properties was observed in Bi-excess compositions and a deterioration in the dielectric properties was observed in Na-excess compositions.Impedance spectroscopy was utilized to analyze the effects of A-site nonstoichiometry on conduction mechanisms.Compositions with Bi-excess resulted in an electrically homogeneous microstructure with an increase in resistivity by3-4 orders of magnitude and an associated activation energy of 1.57 eV which was close to half of the optical bandgap.In contrast,an electrically heterogeneous microstructure was observed in both the stoichiometric and Na-excess compositions.In addition,the Na-excess compositions exhibited low resistivities(ρ-10^(3)Ω-cm)with characteristic peaks in the impedance data comparable to the recent observations of oxide ion conduction in(Bi_(0.5)Na_(0.5))TiO_(3).Long term annealing studies were also conducted at 800℃to identify changes in crystal structure and electrical properties.The results of this study demonstrates that the dielectric and electrical properties of 0.94(Bi_(0.5)Na_(0.5))TiO_(3)-0.06BaTiO_(3)ceramics are very sensitive to Bi/Na stoichiometry. | Sasiporn Prasertpalichat Whitney Schmidt David P.Cann | 2016 | Journal of Advanced Dielectrics2016，6，2： | 0 |
| 4 | Synthesis and electrical properties of BaBiO_(3)and high resistivity BaTiO_(3)-BaBiO_(3)ceramics显示文摘Ceramics of the composition BaBiO_(3)(BB)were sintered in oxygen to obtain a single phase with monoclinic I2/m symmetry as suggested by high-resolution X-ray diffraction.X-ray photoelectron spectroscopy confirmed the presence of bismuth in two valence states—3þand 5þ.Optical spectroscopy showed presence of a direct bandgap at-2.2 eV and a possible indirect bandgap at-0.9 eV.This combined with determination of the activation energy for conduction of 0.25 eV,as obtained from ac impedance spectroscopy,suggested that a polaron-mediated conduction mechanism was prevalent in BB.The BB ceramics were crushed,mixed with BaTiO_(3)(BT),and sintered to obtain BT–BB solid solutions.All the ceramics had tetragonal symmetry and exhibited a normal ferroelectric-like dielectric response.Using ac impedance and optical spectroscopy,it was shown that resistivity values of BT–BB were orders of magnitude higher than BT or BB alone,indicating a change in the fundamental defect equilibrium conditions.A shift in the site occupancy of Bi to the A-site is proposed to be the mechanism for the increased electrical resistivity. | Nitish Kumar Stephen L.Golledge David P.Cann | 2016 | Journal of Advanced Dielectrics2016，6，4： | 0 |
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