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3篇 您的检索式:作者名="DONG Chunfa"
    题名 作者 年代 出处 被引量
1Excitation-wavelength-dependent fluorescent organohydrogel for dynamic information anti-counterfeiting显示文摘Anti-counterfeiting labels with various fluorescent colors are of great importance in information encryption-decryption,but are still limited to static information display.Therefore,it is urgent to develop new materials and encryption-decryption logic for improving the security level of secret information.In this study,an organohydrogel made up of poly(N,N-dimethylacrylamide)(pDMA)hydrogel network and polyoctadecyl methacrylate(pSMA)organogel network that copolymerized with two fluorophores,6-acrylamidopicolinic acid moieties(6APA,fluorescent ligand)and spiropyran units(SPMA,photochromic monomer),was prepared by a two-step interpenetrating method.As UV light of 365nm and 254nm can both cleave C_(spiro)-O bonds of SPMA,and the green fluorescence of 6APA-Tb^(3+) can only be excited by 254nm light,the organohydrogel displays yellow and red under the irradiation of 254nm and 365 nm,respectively.In addition to wavelength selectivity,these two fluorophores are thermal-responsive,leading to the fluorescence variation of the organohydrogel during heating process.As a result,secret information loaded on the organohydrogel can be decrypted by the irradiation of UV light,and the authenticity of the information can be further identified by thermal stimulation.Our fluorescent organohydrogel can act as an effective anti-counterfeiting label to improve the information security and protect the information from being cracked.Dong Guo Xiaoxia Le Hui Shang Fuqing Shan Danyang Li Chunfa Ouyang Tao Chen 2023Chinese Chemical Letters2023,34,11:0
2Effective Microstructure Unit in Control of Impact Toughness in CGHAZ for High Strength Bridge Steel显示文摘The high strength bridge steel was processed with the simulated coarse grain heat affected zone(CGHAZ) thermal cycle with heat input varying from 30 to 60 kJ/cm, the microstructures were investigated by means of optical microscope(OM), scanning electron microscope(SEM), electron backscattering diffraction(EBSD) and transmission electron microscope(TEM), and the impact properties were evaluated from the welding thermal cycle treated samples. The results indicate that the microstructure is primarily composed of lath bainite. With decreasing heat input, both bainite packet and block are significantly refined, and the toughness has an increasing tendency due to the grain refinement. The fracture surfaces all present cleavage or fracture for the samples with different heat inputs. Moreover, the average cleavage facet size for the CGHAZ is nearly equal to the average bainite packet size and the bainitic packet boundary can strongly impede the crack propagation, indicating that the bainitic packet is the most effective unit in control of impact toughness in the simulated CGHAZ of high strength bridge steel.杨秀芝 张李超 史玉升 YU Shengfu DONG Chunfa HUA Wenlin LI Xuan 2018Journal of Wuhan University of Technology(Materials Science)2018,33,1:0
3Functionalizing DNA nanostructures with natural cationic amino acids显示文摘Complexing self-assembled DNA nanostructures with various functional guest species is the key to unlocking new and exciting biomedical applications.Cationic guest species not only induce magnesium-free DNA to self-assemble into defined structures but also endow the final complex nanomaterials with new properties.Herein,we propose a novel strategy that employs naturally occurring cationic amino acids to induce DNA self-assembly into defined nanostructures.Natural L-arginine and L-lysine can readily induce the assembly of tile-based DNA nanotubes and DNA origami sheets in a magnesium-free manner.The self-assembly processes are demonstrated to be pH-and concentration-dependent and are achieved at constant temperatures.Moreover,the assembled DNA/amino acid complex nanomaterials are stable at a physiological temperature of 37◦C.Substituting L-arginine with its D form enhances its serum stability.Further preliminary examination of this complex nanomaterial platform for biomedical applications indicates that DNA/amino acids exhibit distinct cellular uptake behaviors compared with their magnesium-assembled counterparts.The nanomaterial mainly clusters around the cell membrane and might be utilized to manipulate molecular events on the membrane.Our study suggests that the properties of DNA nanostructures can be tuned by complexing them with customized guest molecules for a designed application.The strategy proposed herein might be promising to advance the biomedical applications of DNA nanostructures.Dong Wang Chunfa Chen Qian Liu Qianwen Zhao Di Wu Yue Yuan Chaowang Huang Xiaorong Sun Chunji Huang David Tai Leong Guansong Wang Hang Qian 2021Bioactive Materials2021,6,9:0
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