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| 1 | Recent advances in carbon dioxide capture and utilization with amines and ionic liquids显示文摘Global warming and climate change due to anthropogenic carbon dioxide(CO_(2))have aroused significant concerns at the global scale due to rapid economic growth in industries and other fields.Therefore,CO_(2)capture,use,and storage have become particularly important.In this review,general background and methods for CO_(2)capture and separation,in particular,on ionic liquids(ILs)-based solvents and materials,are discussed.Comprehensive surveys of ILs for CO_(2)absorption are presented,which focused mainly on experimental researches,and then the concept is extended to functionalized absorbents and recent developments for CO_(2)capture.Major advantages and disadvantages of amines-based and ILs-based absorbents are discussed in this review.Solutions of traditional amines(MEA,MDEA,DEA,AMP,PZ,etc.)and ILs(conventional ILs,functionalized ILs,etc.)are summarized.Moreover,research progresses on CO_(2)separation are also introduced focusing mainly on amines and ILs-based membranes(e.g.supported amines membranes,SILMs).Futhermore,the fixation of CO_(2)into cyclic carbonates catalyzed by ILs(pure ILs,complex catalyst system with ILs,supported ILs,etc.)is summarized,clearly explaining the mechanism of CO_(2)fixation with ILs.Finally,exploration of some recent studies about CO_(2)capture and conversion by ILs and challenges for further progress are presented and related suggestions are put forward. | Yuxin Wu Jianhong Xu Kathryn Mumford Geoffrey W.Stevens Weiyang Fei Yundong Wang | 2020 | Green Chemical Engineering2020，1，1： | 9 |
| 2 | The use of environmentally sustainable bio-derived solvents in solvent extraction applications——A review显示文摘Replacement of volatile organic compounds(VOCs) by greener or more environmentally sustainable solvents is becoming increasingly important due to the increasing health and environmental concerns as well as economic pressures associated with VOCs.Solvents that are derived from biomass,namely bio-derived solvents,are a type of green solvent that have attracted intensive investigations in recent years because of their advantages over conventional VOCs,such as low toxicity,biodegradability and renewability.This review aims to summarize the use of bio-derived solvents in solvent extraction applications,with special emphasis given to utilization of biodiesels and terpenes.Compared with the conventional VOCs,the overall performance of these bio-derived solvents is comparable in terms of extraction yields and selectivity for natural product extraction and no difference was found for metal extraction.To date most researchers have focused on laboratory scale thermodynamics studies.Future work is required to develop and test new bio-derived solvents and understand the kinetic performance as well as solvent extraction pilot plant studies. | Zheng Li Kathryn H.Smith Geoffrey W.Stevens | 2016 | Chinese Journal of Chemical Engineering2016，24，2： | 7 |
| 3 | Carbon dioxide capture by solvent absorption using amino acids: A review显示文摘The emission of large amounts of carbon dioxide is of major concern with regard to increasing the risk of climate change. Carbon capture, utilisation and storage (CCUS) has been proposed as an important pathway for slowing the rate of these emissions. Solvent absorption of CO_2 using amino acid solvents has drawn much attention over the last few years due to advantages including their ionic nature, low evaporation rate, low toxicity, high absorption rate and high biodegradation potential, compared to traditional amine solvents. In this review, recent progress on the absorption kinetics of amino acids is summarised, and the engineering potential of using amino acids as carbon capture solvents is discussed. The reaction orders between amino acids and carbon dioxide are typ- ically between 1 and 2. Glycine exhibits a reaction order of 1, whilst, by comparison, lysine, proline and sarcosine have the largest reaction constants with carbon dioxide which is much larger than that of the benchmark solvent monoethanolamine (MEA). Ionic strength, p H and cations such as sodium and potassium have been shown to be important factors influencing the reactivity of amino acids. Corrosivity and reactivity with impurities such as SOx and NOxare not considered to be significant problems for amino acids solvents. The precipitation of CO_2 loaded amino acid salts is thought to be a good pathway for increasing CO_2loading capacity and cutting desorption energy costs if well-controlled. It is recommended that more detailed research on amino acid degradation and overall process energy costs is conducted. Overall, amino acid solvents are recognised as promising potential solvents for car- bon dioxide capture. | Guoping Hu Kathryn H.Smith Yue Wu Kathryn A.Mumford Sandra E.Kentish Geoffrey W.Stevens | 2018 | Chinese Journal of Chemical Engineering2018，26，11： | 3 |
| 4 | Prediction of dispersed phase holdup in pulsed disc and doughnut solvent extraction columns under different mass transfer conditions显示文摘Using experimental data from a number of pulsed disc and doughnut solvent extraction columns,a unified correlation for the prediction of dispersed phase holdup that considers the effects of mass transfer is presented.Pulsed disc and doughnut solvent extraction columns(PDDC) have been used for a range of important applications such as uranium extraction and nuclear fuel recycling.Although the dispersed phase holdup in a PDDC has been presented by some researchers,there is still the need to develop a robust correlation that can predict the experimental dispersed phase holdup over a range of operating conditions including the effects of mass transfer direction.In this study,dispersed phase holdup data from different literature sources for a PDDC were used to refit constants for the correlation presented by Kumar and Hartland [Ind.Eng.Chem.Res.,27(1988),131–138] which did not consider the effect of column geometry.In order to incorporate the characteristic length of the PDDC(i.e.the plate spacing),the unified correlation for holdup proposed by Kumar and Hartland based on data from eight different types of columns [Ind.Eng.Chem.Res.,34(1995) 3925–3940] was refitted to the PDDC data.New constants have been presented for each holdup correlation for a PDDC based on regression analysis using published holdup data from PDDCs that cover a range of operating conditions and physical properties and consider the direction of mass transfer. | Yong Wang Kathryn H.Smith Kathryn Mumford Teobaldo F.Grabin Zheng Li Geoffrey W.Stevens | 2016 | Chinese Journal of Chemical Engineering2016，24，2： | 3 |
| 5 | Modelling of a post-combustion carbon dioxide capture absorber using potassium carbonate solvent in Aspen Custom Modeller显示文摘The process models for an equilibrium CO_2 absorber and a rate based CO_2 absorber using potassium carbonate(K2 CO3) solvents were developed in Aspen Custom Modeller(ACM) to remove CO_2 from a flue gas. The process model utilised the Electrolyte Non-Random Two Liquid(ENRTL) thermodynamic model and various packing correlations. The results from the ACM equilibrium model shows good agreement with an inbuilt Aspen Plus?model when using the same input conditions. By further introducing a Murphree efficiency which is related to mass transfer and packing hydraulics, the equilibrium model can validate the experimental results from a pilot plant within a deviation of 10%. A more rigorous rate based model included mass and energy flux across the interface and the enhancement effect resulting from chemical reactions. The rate based model was validated using experimental data from pilot plants and was shown to predict the results to within 10%. A parametric sensitivity analysis showed that inlet flue gas flowrate and K2 CO3 concentration in the lean solvent has significant impact on CO_2 recovery. Although both models can provide reasonable predictions based on pilot plant results, the rate based model is more advanced as it can explain mass and heat transfer, transport phenomena and chemical reactions occurring inside the absorber without introducing an empirical Murphree efficiency. | Yue Wu Fan Wu Guoping Hu Nouman R.Mirza Geoffrey W.Stevens Kathryn A.Mumford | 2018 | Chinese Journal of Chemical Engineering2018，26，11： | 1 |
| 6 | Preparation of Nanoporous Carbonaceous Promoters for Enhanced CO2 Absorption in Tertiary Amines显示文摘Aqueous solutions of tertiary amines are promising absorbents for CO2 capture,as they are typically characterized by a high absorption capacity,low heat of reaction,and low corrosivity.However,tertiary amines also exhibit very low kinetics of CO2 absorption,which has made them unattractive options for large-scale utilization.Here,a series of novel nanoporous carbonaceous promoters(NCPs)with different properties were synthesized,characterized,and used as rate promoters for CO2 absorption in aqueous N,N-diethylethanolamine(DEEA)solutions.To prepare a DEEA–NCP nanofluid,NCPs were dispersed into aqueous 3 mol∙L1 DEEA solution using ultrasonication.The results revealed that among microporous(GC)and mesoporous(GS)carbonaceous structures functionalized with ethylenediamine(EDA)and polyethyleneimine(PEI)molecules,the GC–EDA promoter exhibited the best performance.A comparison between DEEA–GC–EDA nanofluid and typical aqueous DEEA solutions highlighted that the GC-EDA promoter enhances the rate of CO2 absorption at 40C by 38.6%(36.8–50.7 kPamin1)and improves the equilibrium CO2 absorption capacity(15 kPa;40C)by 13.2%(0.69–0.78 mol of CO2 per mole of DEEA).Moreover,the recyclability of DEEA–GC–EDA nanofluid was determined and a promotion mechanism is suggested.The outcomes demonstrate that NCP–GC–EDA in tertiary amines is a promising strategy to enhance the rate of CO2 absorption and facilitate their large-scale deployment. | Masood S.Alivand Omid Mazaheri Yue Wu Geoffrey W.Stevens Colin A.Scholes Kathryn A.Mumford | 2020 | Engineering2020，6，12： | 0 |
| 7 | Preface显示文摘Every three years the world's leaders in solvent extraction get together at the International Solvent Extraction Conference and in2014 it was held in Wurzburg in Germany.The following are 9 papers that were picked out that show an overview of the work presented and provide an update on some of the research being undertaken in solvent extraction today.For me the trend to environmentally sustainable bio derived solvents is a key | geoffrey w.stevens | 2016 | Chinese Journal of Chemical Engineering2016，24，2： | 0 |
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