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1篇 您的检索式:作者名="Glib V.Baryshnikov"
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1Visualizing Material Processing via Photoexcitation-ControlledOrganic-Phase Aggregation-Induced Emission显示文摘Aggregation-induced emission(AIE)has been much employed for visualizing material aggregation and self-assembly.However,water is generally required for the preparation of the AIE aggregates,the operation of which limits numerous material processing behaviors.Employing hexathiobenzene-based small molecules,monopolymers,and block copolymers as different material prototypes,we herein achieve AIE in pure organic phases by applying a nonequilibrium strategy,photoexcitationcontrolled aggregation.This strategy enabled a dynamic change of molecular conformation rather than chemical structure upon irradiation,leading to a continuous aggregation-dependent luminescent enhancement(up to~200-fold increase of the luminescent quantum yield)in organic solvents.Accompanied by the materialization of the nonequilibrium strategy,photoconvertible self-assemblies with a steady-state characteristic can be achieved upon organic solvent processing.The visual monitoring with the luminescence change covered the whole solution-to-film transition,as well as the in situ photoprocessing of the solid-state materials.Jian Gu Bingbing Yue Glib V.Baryshnikov Zhongyu Li Man Zhang Shen Shen HansÅgren Liangliang Zhu 2021Research2021,,1:1
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