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		题名	作者	年代	出处	被引量
	1	Control of the molecular weight of hyperbranched polyglycerols 显示文摘	Holger Kautz Alexander Sunder Holger Frey	2001	Macromolecular Symposia2001，163，1：	2
	2	Amphiphiliclinear-hyperbranched block copolymers with linear poly ( ethyleneoxide) and hyperbranched poly ( carbosilane ) block 显示文摘	Frederik Wurm Hanna Schu le Holger Frey	2008	Macromolecules2008，41，96：	1
	3	Hyperbranched polymers prepared via the core-dilution/low addition technique: computer simulation of molecular weight distribution and degree of branching显示文摘	Ralf Hanselmann Dirk Holter Holger Frey	1998	Macromolecules1998，31，：	1
	4	Hyper- branched polymers prepared via core - dilution/slow addition tech- nique : Computer simulation of molecular weight distribution and de- gree of branching 显示文摘	RALF HANSELMAN DIRK HOLTER HOLGER FREY	1998	Maeromoleeules1998，31，12：	1
	5	Rainer hagg dendritische polymere fur medizinische anwendungen: auf dem weg zum einsatz in diagnostik und therapie显示文摘	Salah-Eddine Stiriba Holger Frey	2002	Angew Chem Int Ed2002，41，8：	1
	6	Grafting of hyperbranched polymers:From unusual comp\|ex polymer topologies to multivalent surface functionalization 显示文摘	Christoph Schtlll Holger Frey	2013	Polymer2013，54，：	1
	7	Controlled synthesis of hyperbranched polyglycerols by ring-opening multibranching polymerization 显示文摘	Alexander Sunder Ralf Hanselmann Holger Frey	1999	Macromolecules1999，32，13：	1
	8	Aliphatic hyperbranched copolyesters by combination of ROP and AB2-polycondensation显示文摘	Smet Mario Gottschalk Casten Skaria Sunny Frey Holger	2005	Macromolecular Chemistry and Physics2005，206，：	1
	9	Controlled synthesis of lin- ear polymers with highly branched side chains by 'hyper- grafting' : poly ( 4-hydroxy styrene )-grafthyperbranched polyglycerol显示文摘	Schiill Christoph Frey Holger	2012	Macro Lett2012，1，：	1
	10	Optically active amphiphilic hyperbranched polyglycerols as tem- plates for palladium nanoparticles 显示文摘	Chen Yu Holger Frey Ralf Thomann	2006	Inorganica Chimica Acta2006，359，：	1
	11	Hyperbranched polymers prepared via the core - dilution/low addition technique: computer simulation of molecular weight distribution and degree of branching 显示文摘	RALF HANSELMANN DIRK HOLTER HOLGER FREY	1998	Macromolecules1998，，31：	1
	12	Rapid access to polyfunctional lipids with complex architecture via oxyanionic ring-opening polymerization显示文摘	Hofmann Anna Maria Wurm Frederik Frey Holger	2011	Macromolecules2011，44，：	1
	13	Molecular nanocapsules based on amphiphilic hyperbranched polyglycerols显示文摘	Alexander Sunder Michael Kramer Holger Frey	1999	Angew Chem Int Ed1999，38，23：	1
	14	Synthesis and thermal behavior of esterified aliphatic hyperbranched polyether polyols显示文摘	Alexander Sunder Thorsten Bauer Holger Frey	2000	Macromolecules2000，33，4：	1
	15	Monomer-activated Copolymerization of Ethylene Oxide and Epichlorohydrin: In Situ Kinetics Evidences Tapered Block Copolymer Formation显示文摘The monomer-activated anionic ring-opening copolymerization (AROP) of ethylene oxide (EO) and epichlorohydrin (ECH) using tetraoctylammonium bromide as an initiator and triisobutylaluminum (i-Bu3Al) as an activator was studied. The properties of the copolymers as well as the microstructure have been analyzed in detail via an in situ NMR kinetics study. The statistical copolymers exhibited molecular weights ranging from 2350 g·mol^-1 to 38000 g·mol^-1 (measured by SEC, PEG-standards) and moderate dispersities of 1.27-1.44. The thermal property tests revealed both a glass transition and melting for all copolymers, supporting a block-like nature. Applying in situ NMR kinetic measurements, the reactivity ratios of EO and ECH were determined to be strongly disparate, i.e., rEo = 9.2 and rECH = 0.10. This shows that the simple one-pot statistical anionic copolymerization of EO and ECH via the monomer-activated AROP resulted in the formation of strongly tapered, block-like structures. Furthermore, post-polymerization functionalization of the reactive chloromethyl groups by nucleophilic displacement was investigated for the copolymers. Copolymerization of EO and ECH offers a broad platform for further functionalization and therefore the possibility to prepare a variety of multifunctional PEGs.	Ann-Kathrin Danner Daniel Leibig Lea-Marie Vogt Holger Frey	2019	Chinese Journal of Polymer Science2019，37，9：	0

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