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您的检索式：作者名="Haodong Liao"
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| 1 | Self-Stabilized Precipitation Polymerization and Its Application显示文摘An efective,value-added use of the large amounts of olefnic compounds produced in the processing of petroleum,aside from ethylene and propylene,has been a long outstanding challenge.Here,we developed a novel heterogeneous polymerization method,beyond emulsion/dispersion/suspension,termed self-stabilized precipitation(2SP)polymerization,which involves the nucleation and growth of nanoparticles(NPs)of a well-defned size without the use of any stabilizers and multifunctional monomers(crosslinker).Tis technique leads to two revolutionary advances:(1)the generation of functional copolymer particles from single olefnic monomer or complex olefnic mixtures(including C4/C5/C9 fractions)in large quantities,which open a new way to transform huge amount of unused olefnic compounds in C4/C5/C9 fractions into valuable copolymers,and(2)the resultant polymeric NPs possess a self-limiting size and narrow size distribution,therefore being one of the most simple,efcient,and green strategies to produce uniform,size-tunable,and functional polymeric nanoparticles.More importantly,the separation of the NPs from the reaction medium is simple and the supernatant liquid can be reused;hence this new synthetic strategy has great potential for industrial production. | Zhenjie Liu Dong Chen Jinfang Zhang Haodong Liao Yanzhao Chen Yingfa Sun Jianyuan Deng Wantai Yang | 2018 | Research2018，，1： | 3 |
| 2 | Carbon dots regulate the interface electron transfer and catalytic kinetics of Pt-based alloys catalyst for highly efficient hydrogen oxidation显示文摘The regulation of interface electron-transfer and catalytic kinetics is very important to design the efficient electrocatalyst for alkaline hydrogen oxidation reaction(HOR).Here,we show the Pt-Ni alloy nanoparticles(PtNi_(2))have an enhanced HOR activity compared with single component Pt catalyst.While,the interface electron-transfer kinetics of PtNi_(2)catalyst exhibits a very wide electron-transfer speed distribution.When combined with carbon dots(CDs),the interface charge transfer of PtNi_(2)-CDs composite is optimized,and then the PtNi_(2)-5 mg CDs exhibits about 2.67 times and 4.04 times higher mass and specific activity in 0.1 M KOH than that of 20%commercial Pt/C.In this system,CDs also contribute to trapping H^(+)and H_(2)O generated during HOR,tuning hydrogen binding energy(HBE),and regulating interface electron transfer.This work provides a deep understanding of the interface catalytic kinetics of Pt-based alloys towards highly efficient HOR catalysts design. | Jie Wu Yunjie Zhou Haodong Nie Kaiqiang Wei Hui Huang Fan Liao Yang Liu Mingwang Shao Zhenhui Kang | 2022 | Journal of Energy Chemistry2022，31，3： | 1 |
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