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1篇 您的检索式:作者名="Jamie H.Docherty"
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1Iron-Catalysed C(sp^(2))-H Borylation with Expanded Functional Group Tolerance显示文摘Arene C(sp^(2))-H bond borylation offers direct and efficient access to aryl boronic esters.Using in situ catalyst activation and photoirradiation,the iron-catalysed C(sp^(2))-H borylation reaction of carboarenes,pyrroles,and indoles has been developed using only bench-stable pre-catalysts and reagents.Good functional group tolerance was observed including those not reported using previous methods(ArNH_(2),ArOH,ArSiR_(3),ArP(O)(O)_(2),ArC(O)NR_(2)).Mechanistic studies revealed iron-catalysed reductive deoxygenation,C—F protodefluorination,and a demethylation of aryl methyl ethers by C—O sigma bond hydroboration.Luke Britton Jamie H.Docherty Gary S.Nichol Andrew P.Dominey Stephen P.Thomas 2022Chinese Journal of Chemistry2022,40,24:0
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