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2篇 您的检索式:作者名="Jingren He"
    题名 作者 年代 出处 被引量
1Isolation and quantifieation of oligomeric pyranoanthoeyanin-flavanol pigments from red wines by combination of column chromatographic techniques显示文摘Jingren He Celestino Santos-Buelga Nuno Mateus 2006Journal of Chromatography A2006,1134,:1
2Fluorescence detection of phosphate in an aqueous environment by an aluminum-based metal-organic framework with amido functionalized ligands显示文摘The on-site monitoring of phosphate is important for environmental management.Conventional phosphate detection methods are not appropriate to on-site monitoring owing to the use of complicated detection procedures,and the consequent high cost and maintenance requirements of the detection apparatus.Here,a highly sensitive fluorescence-based method for phosphate detection with a wide detection range was developed based on a luminescent aluminum-based metal-organic framework(Al-MOF).The Al-MOF was prepared by introducing amine functional groups to conventional MIL to enhance phosphate binding,and exhibited excellent fluorescence properties that originated from the ligand-to-metal charge transfer(LMCT).The detection limit was as low as 3.25µmol/L(0.10 mg/L)and the detection range was as wide as 3–350µmol/L(0.10–10.85 mg/L).Moreover,Al-MOF displayed specific recognition toward phosphate over most anions and metal cations,even for a high concentration of the co-existent ions.The mechanism of phosphate detection was analyzed through the characterization of the combination of Al-MOF and phosphate,and the results indicated the high affinity between Al-O and phosphate inhibited that the LMCT process and recovered the intrinsic fluorescence of NH2−H2BDC.The recovery of the developed detection method reached a satisfactory range of 85.1%–111.0%,and the feasibility of on-site phosphate detection was verified using a prototype sensor for tap water and lake water samples.It was demonstrated that the prepared Al-MOF is highly promising for on-site detection of phosphate in an aqueous environment.Peng Li Lingqian Dong Han Jin Jingren Yang Yonghui Tu Chao Wang Yiliang He 2022Frontiers of Environmental Science & Engineering2022,16,12:0
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