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3篇 您的检索式:作者名="L.L.Barton"
    题名 作者 年代 出处 被引量
1厌氧菌Shewcenella putrefaciens还原U(Ⅵ)的实验研究:应用于中国层间氧化带砂岩型铀矿显示文摘报道在中国首次模拟新疆某层间氧化带砂岩型铀矿床成矿主要物理化学条件(35℃,Eh≈-0.1 V,pH=7.0-7.4,与现代成矿流体化学成分相近的实验溶液),采用在自然界广泛分布的厌氧菌Shewcenella putrefaciens实验还原U(Ⅵ),迅速地(7昼夜)在该菌胞外壁生成纳米级晶质铀矿(沥青铀矿)沉淀.发现该类沥青铀矿中的大量纳米级(2-4 nm)晶质铀矿单晶,以其排列的完全无序性,区别于有序排列的天然沥青铀矿.最后探讨了该矿床中微生物富集铀的可能机制.本实验结果还可望为核污染水环境的修复和砂岩型铀矿的地浸开采提供生物技术思路.闵茂中 H.F.Xu L.L.Barton 彭新建 尹琳 王汝成 2004中国科学(D辑)2004,34,2:18
2Biomineralization of Uranium: A Simulated Experiment and Its Significance显示文摘A simulated experimental reduction of and the synthesis of uraninite by a sulfate-reducing bacteria, Desulfovibrio desulfuricans DSM 642, are first reported. The simulated physicochemical experimental conditions were: 35°C, pH=7.0-7.4, corresponding to the environments of formation of the sandstone-hosted interlayer oxidation-zone type uranium deposits in Xinjiang, NW China. Uraninite was formed on the surface of the host bacteria after a one-week’s incubation. Therefore, sulfate-reducing bacteria, which existed extensively in Jurassic sandstone-producing environments, might have participated in the biomineralization of this uranium deposit. There is an important difference in the order- disorder of the crystalline structure between the uraninite produced by Desulfovibrio desulfuricans and naturally occurring uraninite. Long time and slow precipitation and growth of uraninite in the geological environment might have resulted in larger uraninite crystals, with uraninite nanocrystals arranged in order, whereas the experimentally produced uraninite is composed of unordered uraninite nanocrystals which, in contrast, result from the short time span of formation and rapid precipitation and growth of uraninite. The discovery has important implications for understanding genetic significance in mineralogy, and also indicates that in-situ bioremediation of U-contaminated environments and use of biotechnology in the treatment of radioactive liquid waste is being contemplated.MINMaozhong HuifangXU L.L.BARTON WANGJinping PENGXinjian H.WIATROWSKI 2005Acta Geologica Sinica(English Edition)2005,79,1:4
3Experimental study on reduction of U (Ⅵ) by an anaerobic bacterium, Shewanella putrefaciens: Application to sandstone-hosted interlayer oxidation-zone type uranium deposits, China显示文摘An experimental study on reduction of U (VI) by anaerobic bacteria, Shewanella putrefaciens, is first reported here in China. The experimental conditions were: 35℃ and pH = 7.0—7.4, corresponding to a physicochemical environments in which the sandstone-hosted in- terlayer oxidation-zone type uranium deposit formed in Northwest China’s Xinjiang. Bacteria adopted in the present experiment, Shewanella putrefaciens, occur extensively in natural envi- ronment. Our study shows that nano-crystal precipitates of uraninite quickly occurred on the surface of the cells within one week. It was found that the pitchblende was characterized by a random arrangement of uraninite nanocrystals (2—4 nm) in it, significantly different from natural pitchblende in which uraninite nanocrystals are arranged in order. Finally, a possible mechanism of uranium biomineralization by microorganisms in the deposits is discussed. Our investigation may supply a technical train of thoughts for bioremediation of nuclear-contaminated water envi- ronments and for underground dissolving extraction of the sandstone-hosted uranium ores.L.L.Barton 2005Science China Earth Sciences2005,48,3:0
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