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2篇 您的检索式:作者名="LI Guike"
    题名 作者 年代 出处 被引量
1Infrared transition properties of vanadium dioxide thin films across semiconductor-metal transition显示文摘Vanadium dioxide thin films were fabricated through annealing vanadium oxide thin films deposited by dual ion beam sputtering. X-ray diffraction (XRD), atom force microscopy (AFM), and Fourier transform infrared spectrum (FTIR) were employed to measure the crystalline structure, surface morphology, and infrared optical transmittance. The phase transition properties were characterized by transmittance. The results show that the annealed vanadium oxide thin film is composed of monoclinic VO2, with preferred orientation of (011). The maximum of transmittance change is beyond 65% as the temperature increases from 20 to 80 C. The reversible changes in optical transmittance against temperature were observed. The change rate of transmittance at short wavelength is higher than that at long wavelength at the same temperature across semiconductor-metal phase transition. This phenomenon was discussed using diffraction effect.LIANG Jiran HU Ming KAN Qiang LIANG Xiuqin WANG Xiaodong LI Guike CHEN Hongda 2011Rare Metals2011,30,3:4
2Electrochemical NO reduction to NH3 on Cu single atom catalyst显示文摘Electrochemical NO reduction reaction(NORR)to generate NH_(3)emerges as a fascinating approach to achieve both NO pollution mitigation and sustainable NH_(3)synthesis.Herein,we demonstrate that single-atomic Cu anchored on MoS_(2)(Cu_(1)/MoS_(2))comprising Cu_(1)-S_(3)motifs can serve as a highly efficient NORR catalyst.Cu1/MoS_(2)exhibits an NH_(3)yield rate of 337.5μmol·h^(−1)·cm^(−2)with a Faradaic efficiency of 90.6%at−0.6 V vs.reversible hydrogen electrode(RHE).Combined experiments and theoretical calculations reveal that Cu1-S3 motifs enable the effective activation and hydrogenation of NO through a mixed pathway and simultaneously retard proton coverage,contributing to the high activity and selectivity of Cu1/MoS_(2)for the NORR.Kai Chen Guike Zhang Xiaotian Li Xiaolin Zhao Ke Chu 2023Nano Research2023,16,4:0
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