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3篇 您的检索式:作者名="Lichuan Pan"
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1Metallogenic controls on the granite-related W–Sn deposits in the Hunan–Jiangxi region, China: evidence from zircon trace element geochemistry显示文摘The Nanling Range in South China is well known for its rich granite-related W–Sn deposits.To elucidate the controls of different granite-related W–Sn metallogenesis in the region,we chose five representative orerelated granites(Yanbei,Mikengshan,Tieshanlong,Qianlishan,and Yaogangxian intrusions)in the Hunan–Jiangxi region,and studied their magmatic zircon ages and trace element geochemistry.Our new zircon data showed the differences in ages,temperatures and oxygen fugacity of the ore-forming magmas.Zircon U–Pb ages of the Yanbei and Mikengshan intrusions are characterized by 142.4±2.4 and 143.0±2.3 Ma,respectively,whereas the Tieshanlong and Qianlishan intrusions are 159.5±2.3and 153.2±3.3 Ma,respectively.The Sn-related intrusions were younger than the W-related intrusions.The Tiin-zircon thermometry showed that there was no systematic difference between the Sn-related Yanbei(680–744℃)and Mikengshan(697–763℃)intrusions and the W-related Tieshanlong(730–800℃),Qianlishan(690–755℃)and Yaogangxian(686–751℃)intrusions.However,the zircon Ce^4+/Ce^3+ratios of the Yanbei(averaged at 18.3)and Mikengshan(averaged at 18.8)intrusions are lower than those of the Tieshanlong(averaged at 36.9),Qianlishan(averaged at 38.4)and Yaogangxian(averaged at 37)intrusions,indicating that the Sn-related granitic magmas might have lower oxygen fugacities than those of the W-related.This can be explained by that,in more reduced magmas,Sn is more soluble than W and thus is more enriched in the residual melt to form Sn mineralization.The difference in source materials between the Sn-related and the W-related granites seems to have contributed to the different redox conditions of the melts.Yuannan Feng Tingguang Lan Lichuan Pan Tingting Liu Shaohua Dong 2019Acta Geochimica2019,38,4:2
2Mechanically robust bamboo node and its hierarchically fibrous structural design显示文摘Although short bamboo nodes function in mechanical support and fluid exchange for bamboo survival,their structures are not fully understood compared to unidirectional fibrous internodes.Here,we identify the spatial heterostructure of the bamboo node via multiscale imaging strategies and investigate its me chanical properties by multimodal mechanical tests.We find three kinds of hierarchical fiber reinforcement schemes that originate from the bamboo node,including spatially tightened interlocking,triaxial interconnected scaffolding and isotropic intertwining.These reinforcement schemes,built on porous vascular bundles,microfibers and more-refined twist-aligned nanofibers,govern the structural stability of the bamboo via hierarchical toughening.In addition,the spatial liquid transport associated with these multiscale fibers within the bamboo node is experimentally verified,which gives perceptible evidence for life-indispensable multidirectional fluid exchange.The functional integration of mechanical reinforcement and liquid transport reflects the fact that the bamboo node has opted for elaborate structural optimization rather than ingredient richness.This study will advance our understanding of biological materials and provide insight into the design of fiber-reinforced structures and biomass utilization.Si-Ming Chen Si-Chao Zhang Huai-Ling Gao Quan Wang LiChuan Zhou Hao-Yu Zhao Xin-Yu Li Ming Gong Xiao-Feng Pan Chen Cui Ze-Yu Wang YongLiang Zhang HengAn Wu Shu-Hong Yu 2023National Science Review2023,10,2:0
3Electric field-driven folding of single molecules显示文摘Folding of molecules is an essential process in nature,and various molecular machines achieve their chemical and mechanical function via controlled folding of molecular conformations.The electric field offers a unique strategy to drive the folding of molecular conformation and to control charge transport through single molecules but remains unexplored.The single-molecule break junction technique provides access to detect the conformational changes via the monitoring of single-molecule conductance,and the electric field between two metal electrodes with nanoscale spacing can provide an extremely strong to achieve in-situ control and detection of molecular folding at the single-molecule level.Here,we use the electric field to control the single-molecule folding using the scanning tunneling microscope break junction(STM-BJ)technique.The electric fields induced folding could lead to a∼1400%conductance change of the single-molecule junctions,and the folding/unfolding process can be in-situ switched at the scale of milliseconds.DFT calculations suggest the conformational control originates from the electric fieldinduced charge injection,and the formation of homoconjugated conformation with the overlapped orbitals.This work provides the first demonstration of electric field-driven molecular folding,which is essential for the understanding of molecular machines in nature and for the design of artificial molecular machines.Saisai Yuan Yu Zhou Tengyang Gao Lichuan Chen Wei Xu Ping Duan Juejun Wang Zhichao Pan Chun Tang Yang Yang Ruiyun Huang Zongyuan Xiao Wenjing Hong 2024Chinese Chemical Letters2024,35,1:0
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