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| 1 | Multi-shelled CuO microboxes for carbon dioxide reduction to ethylene显示文摘The electroreduction of CO2 to valuable chemicals and fuels offers an effective mean for energy storage.Although CO2 has been efficiently converted into C1 products(e.g.,carbon monoxide,formic acid,methane and methanol),its convention into high value-added multicarbon hydrocarbons with high selectivity and activity still remains challenging.Here we demonstrate the formation of multi-shelled CuO microboxes for the efficient and selective electrocatalytic CO2 reduction to C2H4.Such a structure favors the accessibility of catalytically active sites,improves adsorption of reaction intermediate(CO),inhibits the diffusion of produced OH−and promotes C-C coupling reaction.Owing to these unique advantages,the multi-shelled CuO microboxes can effectively convert CO2 into C2H4 with a maximum faradaic efficiency of 51.3%in 0.1 M K2SO4.This work provides an effective way to improve CO2 reduction efficiency via constructing micro-and nanostructures of electrocatalysts. | Dongxing Tan Jianling Zhang Lei Yao Xiuniang Tan Xiuyan Cheng Qiang Wan Buxing Han Lirong Zheng Jing Zhang | 2020 | Nano Research2020，13，3： | 6 |
| 2 | Tuning the selectivity of photoreduction of CO2 to syngas over Pd/layered double hydroxide nanosheets under visible light up to 600 nm显示文摘Photocatalytic reduction of CO2 with H2 O to syngas is an effective way for producing high value-added chemical feedstocks such as methanol and light olefins in industry.Nevertheless,the precise control of CO/H2 ratio from photocatalytic CO2 reduction reaction still poses a great challenge for the further application.Herein,we prepared a series of highly efficient heterostructure based on highly dispersed palladium supported on ultrathin Co Al-layered double hydroxide(LDH).In conjunction with a Ru-complex sensitizer,the molar ratios of CO/H2 can be tuned from 1:0.74 to 1:3 under visible-light irradiation(λ>400 nm).More interestingly,the syngas can be obtained under light irradiation atλ>600 nm.Structure characterization and density functional theory calculations revealed that the remarkable catalytic activity can be due to the supported palladium,which improved the charge transfer efficiency.Meanwhile,more H atoms were used to generate H2 on the supported palladium for further tunable CO/H2 ratio.This work demonstrates a new strategy for harnessing abundant solar-energy to produce syngas from a CO2 feedstock. | Xian Wang Zelin Wang Ya Bai Ling Tan Yanqi Xu Xiaojie Hao Jikang Wang Abdul Hanif Mahadi Yufei Zhao Lirong Zheng Yu-Fei Song | 2020 | Journal of Energy Chemistry2020，29，7： | 5 |
| 3 | Supercritical CO2 produces the visible-light-responsive TiO2/COF heterojunction with enhanced electron-hole separation for highperformance hydrogen evolution显示文摘To construct the heterojunctions of TiO2 with other compounds is of great importance for overcoming its inherent shortages and improving the visible-light photocatalytic performance.Here we propose the construction of TiO2/covalent organic framework(COF)heterojunction with tight connection by a supercritical CO2(SC CO2)method,which helps bridging the transformation paths for photo-induced charge between T i02 and COF.The produced T i02/COF heterojunction performs a H2 evolution of 3,962 nmol·g^-1·h^-1 under visible-light irradiation,which is-25 times higher than that of pure TiO2 and 4.5 folds higher than that of TiO2/COF synthesized by the conventional solvothermal method.This study opens up new possibilities for constructing heterojunctions for solar energy utilization. | Lifei Liu Jianling Zhang Xiuniang Tan Bingxing Zhang Jinbiao Shi Xiuyan Cheng Dongxing Tan Buxing Han Lirong Zheng Fanyu Zhang | 2020 | Nano Research2020，13，4： | 4 |
| 4 | Effects of Al^(3+)doping on the structure and properties of goethite and its adsorption behavior towards phosphate显示文摘Al substitution in goethite is common in soils, and has strong influence on the structure and physicochemical properties of goethite. In this research, a series of Al-doped goethites were synthesized, and characterized by powder X-ray diffraction(XRD), transmission electron microscopy(TEM), X-ray photoelectron spectroscopy(XPS), Fourier transform infrared spectroscopy(FT-IR) and extended X-ray absorption fine structure(EXAFS)spectroscopy. The adsorption behavior of these samples towards PO43-was also investigated. Characterization results demonstrated that increasing Al content in goethite led to a reduction in crystallinity, increase in specific surface area(SSA), and morphology change from needle-like to granular. Rietveld structure refinement revealed that the lattice parameter a remained almost constant and b slightly decreased, but c was significantly reduced, and the calculated crystal density increased. EXAFS analysis demonstrated that the Fe(Al)–O distance in the structure of the doped goethites was almost the same, but the Fe–Fe(Al) distance decreased with increasing Al content. Surface analysis showed that, with increasing Al content, the content of OH groups on the mineral surface increased. The adsorption of phosphate per unit mass of Al-doped goethite increased, while adsorption per unit area decreased owing to the decrease of the relative proportion of(110) facets in the total surface area of the minerals. The results of this research facilitate better understanding of the effect of Al substitution on the structure and properties of goethite and the cycling of phosphate in the environment. | Wei Li Longjun Wang Fan Liu Xiaoliang Liang Xionghan Feng Wenfeng Tan Lirong Zheng Hui Yin | 2016 | Journal of Environmental Sciences2016，28，7： | 4 |
| 5 | Nitrogen-carbon layer coated nickel nanoparticles for efficient electrocatalytic reduction of carbon dioxide显示文摘The application of nickel in electrocatalytic reduction of CO2 has been largely restricted by side reaction (hydrogen evolution reaction) and catalyst poisoning.Here we report a new strategy to improve the electrocatalytic performance of nickel for CO2 reduction by employing a nitrogen-carbon layer for nickel nanoparticles.Such a nickel electrocatalyst exhibits high Faradaic efficiency 97.5% at relatively low potential of-0.61 V for the conversion of CO2 to CO.Density functional theory calculation reveals that it is thermodynamically accomplishable for the reduction product CO to be removed from the catalyst surface,thus avoiding catalyst poisoning.Also,the catalyst renders hydrogen evolution reaction to be suppressed and hence reasonably improves catalytic performance. | Dongxing Tan Chaonan Cui Jinbiao Shi Zhixun Luo Bingxing Zhang Xiuniang Tan Buxing Han Lirong Zheng Jing Zhang Jianling Zhang | 2019 | Nano Research2019，12，5： | 3 |
| 6 | Right anterior cingulate gyrus in encephalic region associated with integrating and processing Chinese words information in working memory: A functional magnetic resonance imaging study显示文摘BACKGROUND: Many experimental results have been found in previous studies on whether laterality of brain cingulate gyrus exists in processing Chinese words information. OBJECTIVE: To observe the function of right anterior cingulate gyrus and activation showed by MRI in processing Chinese words in a visual working memory judgment tasks, and evaluate the laterality of activated brain regions. DESIGN: Observation experiment. SETTING: The Medical Psychological Research Center, Second Xiangya Hospital of Central South University. PARTICIPANTS: Thirteen healthy volunteers (7 males and 6 females), aged (29±7)years ranging from 23 to 36 years old, participated in this fMRI study during August 2003 to Febuary 2004. They gave informed consent in accordance with guidelines set by Second Xiangya Hospital of Central South University. All subjects were native Chinese speakers and strongly right handed. METHODS: In this study, Chinese numeral words were used as test materials and test mode of Sternberg was used in cognitive task, it was aimed to investigate the encephalic region involved in the storage and processing of Chinese numerical information. ①The head of subject was fixed with dense foam pad. Visual working task was performed according to the requests. Verbal working task was that the subject saw target items for four numerals written in Chinese, presenting for 1.5 s and then, after a short time by blank for 3.0 s. The subject saw one numeral presenting for 1.5 s and had to press one button if it was one of the shown numbers and another button if it did not belong to the presented numbers. There were two visual working memory stimuli in each stimulation block. The experiment was conducted in a single run, which consisted of seven blocks of visual working memory tasks. Different Chinese numerals were displayed in each block to avoid any practice effect (The response rate of the whole working memory task was 50%). ②The activation of brain was scanned with a 1.5T MRI scanner (GE Signa Twinspeed) (slice thickness 5 mm, slice gap 1.5 mm, slice parallel to line between pars geniculate and splenium in corpus callosum from corona capitis to superior part of cerebellum, totally 16 to 18 layers). ③The obtained images were pre-processed and statistically analysed with SPM 99 software. The procedure included timeslice adjusted, realigned, nomalized and smoothed. According to experimental task, data from each subject were analysed to obtain t value of each voxel. Brain activation image was got by Student’s t test and statistic was presented by pseudo-color. Statistical parameter image was formed by overlapping brain activation image on three-dimensional structure image, and the threshold value was set at P < 0.05 with ten or more continous voxels (T ≥ 4.64, K ≥ 10 voxels). The brain activation images of all the subjects were calculated and overlapped into mean brain activation images. The regions with different activation density were found out. The activation voxels in regions-of-interest were checked to calculate a laterality index for each condition. The negative value indicated right hemisphere dominance. MAIN OUTCOME MEASURES: fMRI activation and laterality coefficient of Chinese numerial working task. RESULTS: Thirteen healthy subjects participated in the result analysis. ①fMRI activation of Chinese numerial working task: The results showed that the working memory task with Chinese words not only activated left cerebral cortex including left superior frontal gyrus (BA6/10), left middle frontal gyrus (BA9), left inferior frontal gyrus (BA45/9/47), but also activated right cerebral cortex including right middle frontal gyrus (BA10/46/8), right inferior frontal lobe (BA47). Specially, peak activation was located in right anterior cingulate gyrus (BA32) with an activation volume of 879 (voxels). It indicated that superior, middle and inferior frontal gyrus, bilateral Broca regions and anterior cingutate involved in the working memory of Chinese words. ②Asymmertry index : The asymmetry index was -0.47 for frontal lobe, +0.42 for temporal lobe, +0.14 for parietal lobe and -1.00 for occipital lobe. It indicated that the right frontal lobe, left temporal lobe, left parietal lobe and right occipital lobe were more involved in the Chinese numerial working task. CONCLUSION: Brain activation in processing Chinese words in the visual working memory task broadly involves both the left and right hemisphere cortex. And right anterior cingulate gyrus (BA 32) plays an important role in integrating and processing intensive visuospatial ability. | Daxing Wu Lirong Yan Changlian Tan Dewen Hu Wai Cheong Carl Tam Yadong Liu Zongtan Zhou Xiang Wang Ding Liu Shuqiao Yao | 2006 | Neural Regeneration Research2006，1，5： | 2 |
| 7 | Ginger-indirect moxibustion plus acupuncture versus acupuncture alone for chronic fatigue syndrome:a randomized controlled trial显示文摘OBJECTIVE:To assess the efficacy and safety of gingerindirect moxibustion for chronic fatigue syndrome(CFS).METHODS:In this central randomized,controlled trial,290 CFS participants were recruited and randomly allocated to group A(ginger-indirect moxibustion plus acupuncture)or group B(acupuncture alone).The study consisted of a treatment period of 8 weeks with a total of 24 treatments(3 sessions per week,every other day),and a follow-up period of 12 weeks.The outcome was measured by Fatigue Severity Scale(FSS),Psychological Health Report(SPHERE),the Self-rating depression scale(SDS)and the Hamilton anxiety scale(HAMA)at baseline,2,4,6,8,12 and 20 weeks.RESULTS:With the treatment undergoing,the changes of FSS,SPHERE,SDS and HAMA scores in both groups increased gradually,and the effect maintained at the 12th week.Between groups,significantly higher score changes were seen in group A in FSS after 4 weeks treatment(11.94 vs 9.12,95%CI:0.94,4.7)and in SPHERE after 2 weeks treatment(3.7 vs 2.27,95%CI:0.56,2.31).But for SDS and HAMA,the improvement did not differ significantly between groups.No severe adverse events were reported.CONCLUSION:Ginger-indirect moxibustion is a safe and effective intervention to relieve fatigue and accompanying physical symptoms of CFS. | MA Tingting WU Jie YANG Lijie FENG Fen YANG Huilin ZHANG Jinhua ZHONG Yanjin NING Qing HUANG Lirong LIN Youbing YAN Jue CHEN Guiquan HOU Tianshu WANG Li REN Yuanfang TAN Jing | 2022 | Journal of Traditional Chinese Medicine2022，42，2： | 2 |
| 8 | Decomposing the influencing factors of industrial carbon emissions in Shanghai using the LMDI method显示文摘 | Min Zhao Lirong Tan Weiguo Zhang Minhe Ji Yuan Liu Lizhong Yu | 2010 | Energy2010，，6： | 2 |
| 9 | Insights into the phenomenon of an explosive growth and sharp decline in haze:A case study in Beijing显示文摘A severe haze episode occurred in winter in the North China Plain(NCP),and the phenomenon of an explosive growth and sharp decline in PM2.5(particulate matter with an aerodynamic diameter equal to or less than 2.5μm)concentration was observed.To study the systematic causes for this phenomenon,comprehensive observations were conducted in Beijing from November 26 to December 2,2015;during this period,meteorological parameters,LIDAR data,and the chemical compositions of aerosols were determined.The haze episode was characterized by rapidly varying PM2.5 concentration,and the highest PM2.5 concentration reached 667μg/m3.During the haze episode,the NCP was dominated by a weak high-pressure system and continuously low PBL(planetary boundary layer)heights,which are unfavorable conditions for the diffusion of pollutants.The large increases in the concentrations of SNA(SO42-,NO3-and NH4+)during the haze implied that the formation of SNA was the largest contribution.Water vapor also played a vital role in the formation of haze by promoting the chemical transformation of secondary pollutants,which led to higher PM2.5 concentrations.The spatial distributions of PM2.5 in Beijing at different times and the backward trajectories of the air masses also indicated that pollutants from surrounding provinces in particular,contributed to the higher PM2.5concentration. | Wenguang Li Xingang Liu Yuanhang Zhang Qinwen Tan Miao Feng Mengdi Song Lirong Hui Yu Qu Junling An Haokai Gao | 2019 | Journal of Environmental Sciences2019，31，10： | 1 |
| 10 | Brain activation regions in schizophrenia patients performing the game piece memory task显示文摘BACKGROUND:Go,a traditional Chinese chess-like game,requires many unknown functions of the brain including attention,imaging,problem solving and processing of spatial working memory. To date,it remains uncertain whether the intellectual activities required to play Go are related to the frontal lobe. OBJECTIVE:To investigate various patterns of brain region activity while schizophrenic patients and normal subjects engaged in memorizing piece placement in the Chinese game of Go.Spatial working memory was measured in order to validate whether the prefrontal lobe participates in this memory process. DESIGN,TIME AND SETTING:Non-randomized,concurrent control trial was performed at Second Xiangya Hospital of Central South University,between May and December 2004. PARTICIPANTS:A total of nine Chinese schizophrenic patients with no brain or bodily diseases and not undergoing electroshock treatment,who were in accordance with the DSM-Ⅳcriteria for schizophrenia,as well as thirteen healthy staffs and students with matched age,sex,and education were included.Patients and control subjects had no neurological disorders or mental retardation.In addition,all participants were right-handed. METHODS:The cognitive task for functional magnetic resonance imaging was a block design experiment.Both groups were asked to remember the placement of pieces in the Chinese game of Go on a computer screen.A brain activation map was analyzed in SPM99. MAIN OUTCOME MEASURES:Brain responses were compared with regard to activation region size,volume,and asymmetry indices. RESULTS:Compared with the control group,the reaction time was significantly delayed in schizophrenics performing the working memory task(P<0.05).When performing the tasks, normal subjects showed significant activation of the bilateral dorsolateral prefrontal lobe with left dominance;the asymmetry indices were:frontal lobe,+0.32;temporal lobe,0.58;parietal lobe, 0.41;and occipital lobe,-0.34.On the other hand,schizophrenics showed right dominance and had a broader activation region of the prefrontal lobe(asymmetry indices:frontal lobe,-0.10; temporal lobe,+0.38;parietal lobe,+0.24;and occipital lobe,0.00).When comparing the normal group subtracted with the schizophrenic group,no significant lateralization was found in the frontal lobes but significant activation was found in the left anterior central gyrus,left middle frontal gyrus and in both sides of the cingulate gyrus.Comparing the schizophrenic group subtracted with the normal group,there was significant right lateralization of the frontal lobe and abnormally activated regions on both sides of the anterior central gyrus,middle frontal gyrus,left inferior frontal gyrus, right medial frontal gyrus and the right insular lobe. CONCLUSION:Different brain activation regions are involved in memorizing the placement of pieces in Chinese Go between schizophrenia and healthy subjects.Schizophrenics showed right dominance and border activation range,indicating that the prefrontal cortex plays an important role in memory information processing and resource allocation when remembering piece placement in the game of Go. | Daxing WU Huifang Yin Lirong Yan Changlian Tan Dewen Hu Shuqiao Yao | 2009 | Neural Regeneration Research2009，4，2： | 1 |
| 11 | Decomposing the Influencing Factors of Industrial Carbon Emissions in Shang hai Using the LMDI Method显示文摘 | Zhao Min Tan Lirong Zhang Weiguo | 2010 | Energy2010，35，： | 1 |
| 12 | Bipolar absolute differential confocal approach to higher spatial resolution显示文摘 | Weiqian Zhao Jiubin Tan Lirong Qiu | 2004 | Opt Express2004，12，21： | 1 |
| 13 | Bilateral papilledema caused by chronic infantile neurological cutaneous and articular syndrome in a child with a novel (p. D305N) mutation in NLRP3 gene: a case report显示文摘The rare disease of chronic infantile neurological cutaneous and articular(CINCA)syndrome,is caused by the over-secretion of interleukin(IL)-1βdue to a gain-of-function NLRP3 gene mutation in the autosomal chromosome which often involves in eyes.In this report,we studied a 9-year-old girl with CINCA.The eyes were also involved and presented bilateral papilledema.Genetic testing revealed that the symptoms were caused by a novel gene mutation site(c.913G>A,p.D305N)in conservative domain exon-3 of NLRP3 which is gain-function gene of CINCA.The patient had the characteristic facial features,frontal fossa and saddle nose,manifested the generalized urticaria-like skin rash at two weeks after birth,periodic fever 6 months after birth,sensorineural deafness at 7 years old,and bilateral papilledema,aseptic meningitis and knee arthropathy at 9 years old.White cell counts,C-reactive protein increased and intracranial pressure raised to 300 mmH2O.The meningeal thickening enhanced by gadolinium in magnetic resonance imaging(MRI).Based on clinical features and genetic test,the girl was diagnosed bilateral papilledema secondary to CINCA and administered prednisone and lowered intracranial pressure medicine to resolve symptoms.With 3-year follow-up,patient had no inflammatory flare-up with visual acuity improvement.The finding of novel genetic mutation site(p.D305N)in NLRP3 gene expanded genotype spectrum associated with CINCA.This case also expanded the cause spectrum of papilledema and it highlighted systemic disease history for patients with bilateral papilledema. | Li Li Huanfen Zhou Wei Shi Xiaotun Ren Xiaohua Tan Lirong Tian Chunxia Peng | 2021 | Annals of Eye Science2021，，3： | 1 |
| 14 | Eleetroplating nickel- iron alloy on the Diamond surface 显示文摘 | Tan Lirong Wang Yanhui Zang Jianbing | 2009 | Key Engineering Materials2009，，416： | 1 |
| 15 | Allelopathic Effect of Black Pine( Pinus thunbergii) Needles and Litter on Four Cover Plants显示文摘Black pine( Pinus thunbergii) is one of the main afforestation species in the sandy coast and the preferred tree species for landscape green in northern China.Allelopathic activity could be one of the reasons of the sparse vegetation under black pine forests.To explore the allelopathic potential of P.thunbergii,the effects of litter and fresh needles were evaluated against the common cover plants seeds and seedlings,i.e.Tateges erecta,Orychophragmus violaceus,Ophiopogon japonicas and Trifolium repens.The results showed that P.thunbergii possessed allelopathic potential to the accompanying plants.Increasing concentrations of aqueous extracts of needles and litter affected target plant development in different levels.Growth and germination inhibition were directly related to the extract concentrations of needles or litters.Fresh needles played a more important role in the inhibition to target plants than litter because of the less germination rate and biomass in the same concentration.In addition,the adaptability of cover plants to the allelopathic effects of P.thunbergii is obviously different.The sensitivities of the four cover plants to the allelopathic effects of P.thunbergii were in order of T.repens > O.japonicas > O.violaceus > T.erecta.Therefore,T.repens is least suitable for concomitant planting with P.thunbergii,and T.erecta is the most suitable,with other two plants in between in landscape configuration. | Xuqin REN Xuanle LI Jizhong WANG Bin TAN Lirong WANG Yingchun ZHANG | 2018 | Agricultural Biotechnology2018，7，6： | 1 |
| 16 | Decomposing the influencing factors of industrial carbon emissions in Shanghai using the LMDI method显示文摘 | Min Zhao Lirong Tan Weiguo Zhang Minhe Ji Yuan Liu Lizhong Yu | 2010 | Energy2010，，6： | 1 |
| 17 | Decomposing the influencing factors of industrial carbon emissions in Shanghai using the LMDI method 显示文摘 | ZHAO Min TAN Lirong ZHANG Weiguo | 2010 | Energy Policy2010，35，6： | 1 |
| 18 | Sensitive and specific detection of Agrobacterium tumefaciens in soil using a rapid polymerase chain reaction (PCR)显示文摘 | Yang Wei Ji Lei Tan Lirong | 2011 | African Journal of Microbiology Research2011，5，6： | 1 |
| 19 | Mechanistic action of the acute toxicity of Bajitian(Morinda officinalis)in zebrafish embryos显示文摘Objectives:To investigate acute toxicity of Bajitian(Morinda officinalis)in zebrafish embryos.Methods:Zebrafish embryos at 48-h post fertilization(hpf)were exposed to Bajitian ethanol extract for72 h.The causative action of a delay in yolk sac absorption by Bajitian was investigated by RT-PCR analysis of lipid metabolism-related microsomal triglyceride transfer protein(MTP),apolipoprotein CII(ApoC2)and lipogenesis-related liver x receptor(LXR)genes.The effect of Bajitian eliciting an inflammatory response was studied by exposing 72 hpf myeloperoxidase(MPO):GFP transgenic zebrafish embryos to Bajitian extract for 4 h.Assessment was done by TUNEL,caspase-3/7,and RT-PCR analysis of the apoptosis related pathway B-cell lymphoma 2 associated X protein(Bax),Nuclear factor kappa-lightchain-enhancer of activated B cells(NF-k B)genes,neutrophil development-related stem cell leukaemia(SCL)and transcription factor PU.1 genes,to reveal the causative action of Bajitian reducing neutrophils.Results:RT-PCR analysis found that Bajitian extract had no effect on the expression of MTP or ApoC2 genes,but upregulated LXR gene,which might explain the delay in yolk sac absorption.Analysis of the inflammatory response showed that compared with negative controls,Bajitian extract significantly(P<.05)reduced the number of neutrophils in MPO:GFP embryos.TUNEL,caspase-3/7,and RT-PCR analysis of Bax and NF-k B genes found that Bajitian extract did not trigger the cell apoptosis.Further RT-PCR analysis found that Bajitian extract did not affect SCL expression,but did lead to down-regulation of PU.1.The inhibition of neutrophil development/differentiation may explain the decline in the total number of neutrophils following Bajitian treatment,which could be attributed to the anti-inflammatory effects found clinically for this drug.Conclusions:This study demonstrated that Bajitian caused a delay in yolk sac absorption and a decrease neutrophil in zebrafish embryos,which may be related to the inhibition of neutrophil development. | Lirong Tan Min Cheng Gigi Chi Ting Auyeung Oscar Yu Suen Chan Xueping Chen | 2020 | Journal of Traditional Chinese Medical Sciences2020，7，3： | 1 |
| 20 | Decomposing the influencing factors of industrial carbon emissionsin Shanghai using the LMDI method 显示文摘 | Zhao Min Tan Lirong Zhang Weiguo | 2010 | Energy2010，35，6： | 1 |
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