| 1 | Investigation of RQD variation with scanline length and optimal threshold based on three-dimensional fracture network modeling显示文摘Rock-quality designation(RQD) plays a significant role in rock mass analysis and is an important parameter in geotechnical and geological engineering.However,the RQD variation with scanline length has not yet been comprehensively considered in RQD.In this study,three-dimensional fracture network modeling was used to simulate actual rock mass,and numerous scanlines were set in the fracture network for investigation on RQD variation.Models and equations(i.e.,models A-A,N-N,and A-A-S,as well as the Priest-Hudson and Sen-Kazi equations) were summarized for the study.A corrected equation was proposed to eliminate the errors from using the Priest-Hudson and Sen-Kazi equations.In addition,inhomogeneous and anisotropic features were investigated,and the optimal thresholds for RQD calculation were determined,which varied with the study orientation and rock mass feature.When the inhomogeneity was studied in the x direction,the optimal threshold was found to be 4 m.When anisotropy was studied,the optimal threshold was found to be 3 m. | ZHANG Wen CHEN JianPing WANG Qing MA DongHe NIU CenCen ZHANG Wu | 2013 | Chinese Science Bulletin2013，58，7： | 2 |
| 2 | Empirical modeling of normal/cyclo-alkanes pyrolysis to produce light olefins显示文摘Due to the complexity of feedstock,it is challenging to build a general model for light olefins production.This work was intended to simulate the formation of ethylene,propene and 1,3-butadiene in alkanes pyrolysis by referring the effects of normal/cyclo-structures.First,the pyrolysis of n-pentane,n-hexane,n-heptane,n-octane,n-nonane,n-decane,cyclohexane,methylcyclohexane,n-hexane and cyclohexane mixtures,and n-heptane and methylcyclohexane mixtures were carried out at 650–800℃,and a particular attention was paid to the measurement of ethylene,propene and 1,3-butadiene.Then,pseudo-first order kinetics was taken to characterize the pyrolysis process,and the effects of feedstock composition were studied.It was found that chain length and cyclo-alkane content can be qualitatively and quantitively represented by carbon atom number and pseudo-cyclohexane content,which made a significant difference on light olefins formation.Furthermore,the inverse proportional/quadratic function,linear function and exponential function were proposed to simulate the effects of chain length,cycloalkane content and reaction temperature on light olefins formation,respectively.Although the obtained empirical model well reproduced feedstock conversion,ethylene yield and propene yield in normal/cycloalkanes pyrolysis,it exhibited limitations in simulating 1,3-butadiene formation.Finally,the accuracy and flexibility of the present model was validated by predicting light olefins formation in the pyrolysis of multiple hydrocarbon mixtures.The prediction data well agreed with the experiment data for feedstock conversion,ethylene yield and propene yield,and overall characterized the changing trend of 1,3-butadiene yield along with reaction temperature,indicating that the present model could basically reflect light olefins production in the pyrolysis process even for complex feedstock. | Xu Hou Bochong Chen Zhenzhou Ma Jintao Zhang Yuanhang Ning Donghe Zhang Liu Zhao Enxian Yuan Tingting Cui | 2022 | Chinese Journal of Chemical Engineering2022，35，2： | 1 |
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