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2篇 您的检索式:作者名="Mao Danjun"
    题名 作者 年代 出处 被引量
1Ionic liq- uid-assisted hydrothermal synthesis of square BiOBr nano- plates with highly efficient photoeatalytic activity显示文摘Mao Danjun Lti Xiaomeng Jiang Zhifeng 2014Ma- terials Letters2014,118,:1
2Insight into phase structure-dependent soot oxidation activity of K/MnO_(2) catalyst显示文摘In the present study,two nanosized MnO_(2)with β and δ phase structures and potassium loaded MnO_(2)catalysts with varied K loading amounts (denoted as K/MnO_(2)) were prepared.Temperature programmed oxidation and isothermal reactions in loose contact modes were employed to examine the soot oxidation activity of the as-prepared catalysts.Characterization results show that as compared with β-MnO_(2),δ-MnO_(2)has larger surface area and higher content of hydroxyl groups.Upon K loading,abundant hydroxyl groups in δ-MnO_(2)effectively sequestrate K cation to form bound K species and free K species are available only at K loading above 3.0 wt.%.In contrast,the majority of K species present as free state in β-MnO_(2)even at a K loading of 1.0 wt.%due to its very low hydroxyl group content.The O_(2)temperature-programmed desorption (O_(2)-TPD) demonstrates that the catalysts with free K species exhibit strong ability in activating gaseous O_(2),whereas the catalysts only having bound K display minor O_(2)activation capability.As a result,despite of slightly lower activity of β-MnO_(2)than δ-MnO_(2),the K/β-MnO_(2)catalysts exhibit substantially higher activities than K/δ-MnO_(2)catalysts with identical K loadings.The finding in this study clearly demonstrates that for MnO_(2)based catalysts,the enhancement of catalytic activity for soot oxidation is highly K loading amount dependent and the dependency is strongly associated with the phase structure of MnO_(2).Changlong Zheng Shidong Bao Danjun Mao Zhaoyi Xu Shourong Zheng 2023Journal of Environmental Sciences2023,,4:0
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